- Synthesis of Well-Defined Photo-Cross-Linked Polymeric Nanocapsules by Surface-Initiated RAFT Polymerization
[作者:Huang, X; Appelhans, D; Formanek, P; Simon, F; Voit, B,期刊:Macromolecules, 页码:8351-8360 , 文章类型: Article,,卷期:2011年44-21]
- Narrowly distributed hollow polymeric nanocapsules (PtBMA-co-PDMIPM-b-PHPMA), with the size of 450 or 900 nm, were first synthesized by surface-initiated reversible addition-fragmentation chain transfer (RAFT) polymeriza...
- Origin of the Difference between Branching in Acrylates Polymerization under Controlled and Free Radical Conditions: A Computational Study of Competitive Processes
[作者:Konkolewicz, D; Sosnowski, S; D'hooge, DR; Szymanski, R; Reyniers, MF; Marin, GB; Matyjaszewski, K,期刊:Macromolecules, 页码:8361-8373 , 文章类型: Article,,卷期:2011年44-21]
- A computational study of the branching in polyacrylates is performed for both atom-transfer radical polymerization (ATRP) and free radical polymerization (FRP). In both cases the secondary radical formed can transfer to ...
- A Breakthrough toward Long Wavelength Cationic Photopolymerization: Initiating Systems Based on Violanthrone Derivatives and Silyl Radicals
[作者:Tehfe, MA; Lalevee, J; Morlet-Savary, F; Graff, B; Fouassier, JP,期刊:Macromolecules, 页码:8374-8379 , 文章类型: Article,,卷期:2011年44-21]
- The silyl radical chemistry is used here for the free radical promoted cationic polymerization (FRPCP) of epoxy monomers ((3,4-epoxycyclohexane)methyl 3,4-epoxycyclohexylcarboxylate EPOX and limonene dioxide LDO) and the...
- Regioselective Cyclopolymerization of 1,7-Octadiynes
[作者:Naumann, S; Unold, J; Frey, W; Buchmeiser, MR,期刊:Macromolecules, 页码:8380-8387 , 文章类型: Article,,卷期:2011年44-21]
- The regioselective cyclopolymerization of two structurally different 1,7-octadiynes, i.e. of 1,4-dihexyloxy-2,3-dipropargylbenzene (M1) and (R,R)/(S,S)-4,5-bis(trimethylsilyloxy)-1,7-octadiyne (M2) has been achieved with...
- Quantitative Analysis of the Effect of Azo Initiators on the Structure of alpha-Polymer Chain Ends in Degenerative Chain-Transfer-Mediated Living Radical Polymerization Reactions
[作者:Nakamura, Y; Kitada, Y; Kobayashi, Y; Ray, B; Yamago, S,期刊:Macromolecules, 页码:8388-8397 , 文章类型: Article,,卷期:2011年44-21]
- The effects of azo initiators on the structures of the alpha-polymer chain ends in organotellurium-, organostibine-, organobismuthine-, and organoiodine-mediated living radical polymerizations (TERP, SBRP, BIRP, and IRP,...
- Comb like Thermoresponsive Polymers with Sharp Transitions: Synthesis, Characterization, and Their Use as Sensitive Colorimetric Sensors
[作者:Liu, LX; Li, W; Liu, K; Yan, JT; Hu, GX; Zhang, AF,期刊:Macromolecules, 页码:8614-8621 , 文章类型: Article,,卷期:2011年44-21]
- The synthesis and thermoresponsive behavior of two structural novel comblike polymers are presented, which are constituted by polymethacrylates main chain with dendritic oligoethylene glycol (OEG) side groups spaced with...
- Architectural Dispersity in Model Branched Polymers: Analysis and Rheological Consequences
[作者:Snijkers, F; van Ruymbeke, E; Kim, P; Lee, H; Nikopoulou, A; Chang, T; Hadjichristidis, N; Pathak, J; Vlassopoulos, D,期刊:Macromolecules, 页码:8631-8643 , 文章类型: Article,,卷期:2011年44-21]
- We combine state-of-the-art synthetic, chromatographic, rheological, and modeling techniques in order to address the role of architectural polydispersity in the rheology of model branched polymers. This synergy is shown ...
- On the Apparent SEC Molecular Weight and Polydispersity Reduction upon Intramolecular Collapse of Polydisperse Chains to Unimolecular Nanoparticles
[作者:Pomposo, JA; Perez-Baena, I; Buruaga, L; Alegria, A; Moreno, AJ; Colmenero, J,期刊:Macromolecules, 页码:8644-8649 , 文章类型: Article,,卷期:2011年44-21]
- When unimolecular particles of molecular weight M are formed by intramolecular cross-linking of individual polymer chains, a significant reduction in hydrodynamic radius and, hence, apparent molecular weight (M(app)) is ...
- Multiscale Simulation Study on the Curing Reaction and the Network Structure in a Typical Epoxy System
[作者:Liu, H; Li, M; Lu, ZY; Zhang, ZG; Sun, CC; Cui, T,期刊:Macromolecules, 页码:8650-8660 , 文章类型: Article,,卷期:2011年44-21]
- We propose a multiscale simulation strategy to study the interplay between diffusion and curing reaction on the network formation and the corresponding mechanical properties of epoxy resins. Atomistic molecular dynamics ...
- Peculiar Nonlinear Elasticity of Polyrotaxane Gels with Movable Cross-Links Revealed by Multiaxial Stretching
[作者:Bitoh, Y; Akuzawa, N; Urayama, K; Takigawa, T; Kidowaki, M; Ito, K,期刊:Macromolecules, 页码:8661-8667 , 文章类型: Article,,卷期:2011年44-21]
- A peculiar rubber elasticity feature of polyrotaxane (PR) gels with cross-links capable of moving along network strands is revealed by general biaxial strain testing that varies the strains in the two orthogonal directio...
- Characterization of Surface Viscoelasticity and Energy Dissipation in a Polymer Film by Atomic Force Microscopy
[作者:Wang, D; Liang, XB; Liu, YH; Fujinami, S; Nishi, T; Nakajima, K,期刊:Macromolecules, 页码:8693-8697 , 文章类型: Article,,卷期:2011年44-21]
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