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  • An Approach to the Core Structure of Leiodermatolide
    [作者:RINK CHRISTIAN; NAVICKAS VAIDOTAS; MAIER MARTIN E,期刊:Organic Letters, 页码:2334-2337 , 文章类型: Article,,卷期:2011年13-9]
  • The synthesis of the 16-membered core structure of leiodermatolide 40 has been achieved in 26 linear steps starting from (R)-Roche ester. The key steps in the synthesis of 40 are a Stille cross-coupling between two main ...
  • Rhodium(NHC)-Catalyzed O-Arylation of Aryl Bromides
    [作者:KIM HYUN JIN; KIM MIN; CHANG SUKBOK,期刊:Organic Letters, 页码:2368-2371 , 文章类型: Article,,卷期:2011年13-9]
  • The first example of the rhodium-catalyzed O-arylation of aryl bromides is reported. While the right combination of rhodium species and N-heterocyclic carbene (NHC) offered an effective catalytic system enabling the aryl...
  • A Convergent Route to the CDEF-Tetracycle of Pectenotoxin-2
    [作者:CANTERBURY DANIEL P; MICALIZIO GLENN C,期刊:Organic Letters, 页码:2384-2387 , 文章类型: Article,,卷期:2011年13-9]
  • A convergent synthesis of the CDEF-tetracyclic region of pectenotoxin-2 (PTX-2) is described. The synthetic pathway derives from a head-to-tail union of 2 equiv of linalool to establish a stereodefined DEF-tricyclic alde...
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