- Enabling the Synthesis of Perfluoroalkyl Bicyclobutanes via 1,3 gamma-Silyl Elimination
[作者:KELLY CHRISTOPHER B; COLTHART ALLISON M; CONSTANT BRAD D; CORNING SEAN R; DUBOIS LILY N E; GENOVESE JACQUELINE T; RADZIEWICZ JULIE L; SLETTEN ELLEN M; WHITAKER KATHERINE R; TILLEY LEON J,期刊:Organic Letters, 页码:1646-1649 , 文章类型: Article,,卷期:2011年13-7]
- Two new bicyclobutanes were prepared from cyclobutyl systems by a novel, solvolytic, carbocation-based methodology. An electron-withdrawing perfluoroalkyl group at the incipient cationic center enhances neighboring-group...
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