Inductive effects account for 1/3 of the enhanced acidity of phenol vs. cyclohexanol, 2/5 of the enhanced acidity of enol vs. methanol, and 1/4 of the enhanced acidity of carbonyl a-H's vs. methane.
The laser flash photolysis process of diazomethane has been studied by using a real time propagation time-dependent d. functional theory (RTP-TDDFT) combined with mol. dynamics. The activation energy barrier for disinte...