- Oxidative conversion of functionalized 3,4-dihydropyrimidin-2(1H)-ones to the corresponding pyrimidin-2(1H)-ones using activated carbon-molecular oxygen system.
[作者:Okunaga, Ken-ichi;Nomura, Yukiko;Kawamura, Kenjiro;Nakamichi, Natsuki;Eda, Kazuo;Hayashi, Masahiko;,期刊:Heterocycles, 页码:715-726 , 文章类型: 研究论文,,卷期:2008年76-1]
- Efficient synthesis of functionalized pyrimidin-2(1H)-ones was achieved by oxidn. of 3,4-dihydropyrimidin-2(1H)-ones (DHPMs) using activated carbon-mol. oxygen system. Various DHPMs were easily prepd. by Biginelli react...
- 2-Alkylidene-1,3-dithiane monoxides as activated alkenes in rhodium-catalyzed addition reaction of arylboronic acids.
[作者:Yoshida, Suguru;Yorimitsu, Hideki;Oshima, Koichiro;,期刊:Heterocycles, 页码:679-688 , 文章类型: 研究论文,,卷期:2008年76-1]
- 2-Methylene-1,3-dithiane 1-oxide reacts with arylboronates in the presence of a Rh catalyst in aq. dioxane to afford 2-arylmethyl-1,3-dithiane 1-oxides in good yields.
- Structural aspects of iodine-promoted one-pot cyclization of o-bis(methylthio)stilbenes to thieno[3,2-b]thiophene derivatives: synthetic trials of tetrathienoacenes from 1,2-bis(3-methylthiothiophen-2-yl)ethenes.
[作者:Yamamoto, Tatsuya;Miyazaki, Eigo;Takimiya, Kazuo;,期刊:Heterocycles, 页码:583-593 , 文章类型: 研究论文,,卷期:2008年76-1]
- Attempted reactions for the synthesis of tetrathienoacenes from 1,2-bis[3-(methylthio)thien-2-yl]ethenes by I2-promoted 1-pot cyclization were described. X-ray structural anal. on the precursors indicated that the failu...
- Diene-transmissive hetero-Diels-Alder cycloaddition using cross-conjugated dioxatrienes: a novel synthesis of tetrahydropyran-fused aza- and thia-heterocycles.
[作者:Saito, Takao;Kobayashi, Satoru;Otani, Takashi;Iwanami, Hideoki;Soda, Takayuki;,期刊:Heterocycles, 页码:227-235 , 文章类型: 研究论文,,卷期:2008年76-1]
- The diene-transmissive hetero-Diels-Alder methodol. was developed using cross-conjugated dioxatrienes, substituted 2-(methylene)propanedials. The initial cycloaddn. with electron-rich dienophiles, followed by the reacti...
- Stereoselective preparation and Cope rearrangement of 2-CF3-cis-2,3-bis(alkenyl)oxiranes: a facile route to 2-CF3-substituted oxacycles.
[作者:Shimizu, Masaki;Fujimoto, Takuya;Liu, Xinyu;Takeda, Youhei;Hiyama, Tamejiro;,期刊:Heterocycles, 页码:329-351 , 文章类型: 研究论文,,卷期:2008年76-1]
- A facile route to 2-(trifluoromethyl)-4,5-dihydrooxepins is described, which involves stereoselective prepn. and Cope rearrangement of 2-trifluoromethyl-cis-2,3-bis(alkenyl)oxiranes. Treatment of 1,1-dichloro-2-hydroxy-...
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