- Effect of Free Volume on Water and Salt Transport Properties in Directly Copolymerized Disulfonated Poly(arylene ether sulfone) Random Copolymers
[作者:Xie, W; Ju, H; Geise, GM; Freeman, BD; Mardel, JI; Hill, AJ; McGrath, JE,期刊:Macromolecules, 页码:4428-4438 , 文章类型: Article,,卷期:2011年44-11]
- The influence of cation form and degree of sulfonation on free volume, as probed via positron annihilation lifetime spectroscopy (PALS), and water and salt transport properties was determined in a systematic series of di...
- Diameter-Dependent Modulus and Melting Behavior in Electrospun Semicrystalline Polymer Fibers
[作者:Liu, Y; Chen, S; Zussman, E; Korach, CS; Zhao, W; Rafailovich, M,期刊:Macromolecules, 页码:4439-4444 , 文章类型: Article,,卷期:2011年44-11]
- Confinement of the semicrystalline polymers, poly(ethylene-co-vinyl acetate) (PEVA) and low-density polyethylene (LDPE), produced by electrospinning has been observed to produce fibers with large protrusions, which have ...
- Relaxation of Single Polymer Chain in Poly(methyl methacrylate) Films under Uniaxial Extension Observed by Scanning Near-Field Optical Microscopy
[作者:Ube, T; Aoki, H; Ito, S; Horinaka, J; Takigawa, T; Masuda, T,期刊:Macromolecules, 页码:4445-4451 , 文章类型: Article,,卷期:2011年44-11]
- Single chain conformations during the stress relaxation process in uniaxially stretched poly(methyl methacrylate) (PMMA) films were observed in real space by scanning near-field optical microscopy (SNOM). The extension r...
- 2D-Infrared Thermography Monitoring of Ultrasound-Assisted Polymerization of Water-Soluble Monomer in a Gel Process
[作者:Rigolini, J; Bombled, F; Ehrenfeld, F; El Omari, K; Le Guer, Y; Grassl, B,期刊:Macromolecules, 页码:4462-4469 , 文章类型: Article,,卷期:2011年44-11]
- This paper describes a process based on the ultrasound-assisted polymerization of a water-soluble monomer at a high concentration, which is known as a gel polymerization process. Polymerization is triggered by the ultras...
- Structural Investigation on Thermoresponsive PVA/Poly(methacrylate-co-N-isopropylacrylamide) Microgels across the Volume Phase Transition
[作者:Ghugare, SV; Chiessi, E; Fink, R; Gerelli, Y; Scotti, A; Deriu, A; Carrot, G; Paradossi, G,期刊:Macromolecules, 页码:4470-4478 , 文章类型: Article,,卷期:2011年44-11]
- Characterization of switchable microgels is a major task in drug delivery science. The study of soft polymeric devices requires a combined use of spectroscopy, microscopy, and scattering approaches enabling the character...
- Poly(N-vinylimidazole)-/-Poly(tetrahydrofuran) Amphiphilic Copetworks and Gels: Synthesis, Characterization, Thermal and Swelling Behavior
[作者:Fodor, C; Kali, G; Ivan, B,期刊:Macromolecules, 页码:4496-4502 , 文章类型: Article,,卷期:2011年44-11]
- A novel class of amphiphilic conetworks (APCNs), poly(N-vinylimidazole)-l-poly(tetrahydrofuran) (PVIm-l-PTHF) ("l" stands for "linked by"), was prepared by free radical copolymerization of telechelic PTHF dimethacrylate ...
- Bond Tension in Tethered Macromolecules
[作者:Sheiko, SS; Panyukov, S; Rubinstein, M,期刊:Macromolecules, 页码:4520-4529 , 文章类型: Article,,卷期:2011年44-11]
- The paper presents scaling analysis of mechanical tension generated in densely branched macromolecules tethered to a solid substrate with a short linker. Steric repulsion between branches results in z-fold amplification ...
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