- Strong Bronsted Acid as a Highly Efficient Promoter for Group Transfer Polymerization of Methyl Methacrylate
[作者:Kakuchi, R; Chiba, K; Fuchise, K; Sakai, R; Satoh, T; Kakuchi, T,期刊:Macromolecules, 页码:8747-8750 , 文章类型: Article,,卷期:2009年42-22]
- The Bronsted acid, trifluoromethanesulfonimide (HNTf2), was revealed to act as a highly efficient activator for group transfer polymerization (GTP) of methyl methacrylate (MMA) at ambient temperature. The HNTf2-catalyzed...
- Room-Temperature, Aqueous-Phase Fabrication of Poly(methacrylic acid) Brushes by UV-LED-Induced, Controlled Radical Polymerization with High Selectivity for Surface-Bound Species
[作者:Heeb, R; Bielecki, RM; Lee, S; Spencer, ND,期刊:Macromolecules, 页码:9124-9132 , 文章类型: Article,,卷期:2009年42-22]
- Poly(methacrylic acid) (PMAA) brushes were grafted from Si/SiO2 substrates by means of immobilized-photoiniferter-mediated controlled radical polymerization. The employed UV setup was based on ultraviolet light-emitting ...
- Design, Synthesis, and Multiple Hierarchical Ordering of a Novel Side-Chain Liquid Crystalline-Rod Diblock Copolymer
[作者:Xie, HL; Liu, YX; Zhong, GQ; Zhang, HL; Chen, EQ; Zhou, QF,期刊:Macromolecules, 页码:8774-8780 , 文章类型: Article,,卷期:2009年42-22]
- A novel double liquid crystalline (LC) block copolymer (BCP) composed of poly[omega-(4'-methoxybiphenyl-4-yloxy)hexyl methacrylate] (PMBHMA) and poly{2,5-bis[(4-meth-oxyphenyl)oxycarbonyl]styrene} (PMPCS) was designed an...
- Ion-Induced Stretching of Low Generation Dendronized Polymers with Crown Ether Branching Units
[作者:Ossenbach, A; Ruegger, H; Zhang, A; Fischer, K; Schluter, AD; Schmidt, M,期刊:Macromolecules, 页码:8781-8793 , 文章类型: Article,,卷期:2009年42-22]
- Synthesis of the first (G1) and second generation (G2) dendronized macromonomers MG1 and MG2 with the dibenzo-24-crown-8 moiety as branching unit is reported. The corresponding dendronized polymers, the polymethacrylates...
- Microsphere Pattern Prepared by a "Reverse" Breath Figure Method
[作者:Xiong, XP; Zou, WW; Yu, ZJ; Duan, JJ; Liu, XJ; Fan, SH; Zhou, H,期刊:Macromolecules, 页码:9141-9146 , 文章类型: Article,,卷期:2009年42-22]
- We have reported an interesting method, named reverse breath figure, for the preparation of polymeric microsphere patterns. By the same procedure as breath figure, instead of under a humid atmosphere, linear and star-sha...
- Conformational Behavior of a Series of N-Isopropylacrylamide-Bromostyrene Statistical Copolymers via Phosphorescence Measurements
[作者:Soutar, I; Swanson, L; Adamson, PG; Flint, NJ,期刊:Macromolecules, 页码:9153-9160 , 文章类型: Article,,卷期:2009年42-22]
- This paper reports on the first observation of phosphorescence emission in a thermoresponsive polymer in aqueous media. Random copolymerization of N-isopropylacrylamide, NIPAM, with bromostyrene, BrSTY, promotes efficien...
- Prediction of the Ionic Liquid Influence on Propagation Rate Coefficients in Methyl Methacrylate Radical Polymerizations Based on Kamlet-Taft Solvatochromic Parameters
[作者:Jelicic, A; Garcia, N; Lohmannsroben, HG; Beuermann, S,期刊:Macromolecules, 页码:8801-8808 , 文章类型: Article,,卷期:2009年42-22]
- Pulsed laser initiated polymerizations of methyl methacrylate (MMA) in the presence of ionic liquids (ILs) resulted in a strong enhancement of the propagation rate coefficient, k(p), compared to the bulk system. To corre...
- Functionalized Conjugated Microporous Polymers
[作者:Dawson, R; Laybourn, A; Clowes, R; Khimyak, YZ; Adams, DJ; Cooper, AI,期刊:Macromolecules, 页码:8809-8816 , 文章类型: Article,,卷期:2009年42-22]
- A range of conjugated microporous polymer networks has been prepared using Sonogashira-Hagihara cross-coupling of 1,3,5-triethynylbenzcne with a number of functionalized dibromobenzenes. Porous poly(arylene ethynylene) n...
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