- Highly Sterically Hindered Olefins: A Case of E- and Z-Di-tert-butyl a,b-Unsaturated Acids.
[作者:Ionkin, Alex S.;Marshall, William J.;Fish, Brian M.;,期刊:Organic Letters, 页码:2303-2305 , 文章类型: 研究论文,,卷期:2008年10-11]
- Use of a superbase in the Favorskii rearrangement of 3,5-dibromo-2,2,6,6-tetramethyl-4-heptanone resulted in the synthesis of highly sterically hindered olefins, (E)- and (Z)-2-tert-butyl-4,4-dimethyl-2-pentenoic acids. ...
- Stereodivergent Catalytic Doubly Diastereoselective Nitroaldol Reactions Using Heterobimetallic Complexes.
[作者:Sohtome, Yoshihiro;Kato, Yuko;Handa, Shinya;Aoyama, Naohiro;Nagawa, Keita;Matsunaga, Shigeki;Shibasaki, Masakatsu;,期刊:Organic Letters, 页码:2231-2234 , 文章类型: 研究论文,,卷期:2008年10-11]
- Stereodivergent construction of three contiguous stereocenters in catalytic doubly diastereoselective nitroaldol reactions of a-chiral aldehydes, e.g. I (R1 = Me, PhCH2, EtO2CCH2CH2; R2 = Boc, Cbz), with nitroacetaldehyd...
- Mn-Mediated Coupling of Alkyl Iodides and Ketimines: A Radical Addition Route to a,a-Disubstituted a-Aminoesters.
[作者:Friestad, Gregory K.;Ji, An;,期刊:Organic Letters, 页码:2311-2313 , 文章类型: 研究论文,,卷期:2008年10-11]
- Coupling of primary and secondary alkyl iodides with N-acylhydrazonoesters via Mn-mediated photolysis conditions affords access to tert-alkyl amines RMeC(NHBz)CO2Me (R = Et, iso-Pr, iso-Bu, n-C12H25, etc.).
- Nagelamides K and L, Dimeric Bromopyrrole Alkaloids from Sponge Agelas species.
[作者:Araki, Atsushi;Kubota, Takaaki;Tsuda, Masashi;Mikami, Yuzuru;Fromont, Jane;Kobayashi, Jun'ichi;,期刊:Organic Letters, 页码:2099-2102 , 文章类型: 研究论文,,卷期:2008年10-11]
- Two new dimeric bromopyrrole alkaloids, nagelamides K (I) and L (II), have been isolated from Okinawan marine sponges Agelas species, and the structures and stereochem. were elucidated from spectroscopic data. Nagelamid...
- "Click" saccharide/b-lactam hybrids for lectin inhibition.
[作者:Palomo, Claudio;Aizpurua, Jesus M.;Balentova, Eva;Azcune, Itxaso;Santos, J. Ignacio;Jimenez-Barbero, Jesus;Canada, Javier;Miranda, Jose Ignacio;,期刊:Organic Letters, 页码:2227-2230 , 文章类型: 研究论文,,卷期:2008年10-11]
- carbohydrate recognition domains in selectins have been prepd. according to a "shape-modulating linker" design. This approach was implemented using the azide-alkyne "click" cycloaddn. reaction, and as shown by NMR/MD ex...
- One-Way Biohydrogen Transfer for Oxidation of sec-Alcohols.
[作者:Lavandera, Ivan;Kern, Alexander;Resch, Verena;Ferreira-Silva, Bianca;Glieder, Anton;Fabian, Walter M. F.;de Wildeman, Stefaan;Kroutil, Wolfgang;,期刊:Organic Letters, 页码:2155-2158 , 文章类型: 研究论文,,卷期:2008年10-11]
- Quasi-irreversible oxidn. of sec-alcs. was achieved via biocatalytic hydrogen transfer reactions using alc. dehydrogenases employing selected ketones as hydrogen acceptors, which can only be reduced but not oxidized. Th...
- Thiophene Donor-Acceptor [2]Rotaxanes.
[作者:Ikeda, Taichi;Higuchi, Masayoshi;Sato, Akira;Kurth, Dirk G.;,期刊:Organic Letters, 页码:2215-2218 , 文章类型: 研究论文,,卷期:2008年10-11]
- A series of the thiophene donor-acceptor [2]rotaxanes have been synthesized based on the inclusion complexes of cyclobis(paraquat-p-phenylene) (CBPQT4+) with thiophene, bithiophene, and terthiophene. The max. wavelength...
- A Pentiptycene-Derived Light-Driven Molecular Brake.
[作者:Yang, Jye-Shane;Huang, Yao-Ting;Ho, Jinn-Hsuan;Sun, Wei-Ting;Huang, Hsin-Hau;Lin, Ying-Chih;Huang, Shing-Jong;Huang, Shou-Ling;Lu, Hsiu-Feng;Chao, Ito;,期刊:Organic Letters, 页码:2279-2282 , 文章类型: 研究论文,,卷期:2008年10-11]
- A room-temp. light-driven mol. brake I consisting of a pentiptycene rotator, a 3,5-dinitrophenyl brake, and a photoisomerizable ethenyl spacer, is reported. The rotation rates of the rotator differ by about 9 orders of ...
- 1,2-H Shift in Copper-Chlorocarbenoid Intermediate during CuCl/bpy-Promoted Stereoselective Dechlorination of 2,2,2-Trichloroethyl Alkyl Ethers to (Z)-1-Alkoxy-2-chloroethenes.
[作者:Ram, Ram N.;Manoj, T. P.;,期刊:Organic Letters, 页码:2243-2246 , 文章类型: 研究论文,,卷期:2008年10-11]
- CuCl/bpy in refluxing DCE yielded (Z)-1-alkoxy-2-chloroethenes stereoselectively as the major product via 1,2-H shift in copper-chlorocarbenoid intermediate. 2,2,2-Trichloroethyl carboxylates undergo a radical 1,2-acylo...
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