- Enantioselective Synthesis Utilizing Enantiomorphous Organic Crystal of Achiral Benzils as a Source of Chirality in Asymmetric Autocatalysis.
[作者:Kawasaki, Tsuneomi;Harada, Yuuki;Suzuki, Kenta;Tobita, Takayuki;Florini, Nicola;Palyi, Gyula;Soai, Kenso;,期刊:Organic Letters, 页码:4085-4088 , 文章类型: 研究论文,,卷期:2008年10-18]
- Chiral crystals of achiral benzils act as efficient chiral initiators of asym. autocatalysis to afford highly enantioenriched pyrimidyl alkanols whose abs. configurations depend upon the enantiomorph of the crystal used ...
- Synthesis of a Novel Tricyclic Peptidomimetic Scaffold.
[作者:Sellstedt, Magnus;Almqvist, Fredrik;,期刊:Organic Letters, 页码:4005-4007 , 文章类型: 研究论文,,卷期:2008年10-18]
- Nonracemic oxopyrazolopyridothiazolecarboxylates I (R = Ph, cyclopropyl; R1 = H, Br, Me2CHCH2, Ph, 4-MeOC6H4, 3-O2NC6H4, 3-furanyl, 2-MeC6H4, 1-naphthyl; R2 = H, Me) are prepd. as peptidomimetic scaffolds from nonracemic...
- Stereochemistry of the Singlet Oxygenation of Simple Alkenes: A Stereospecific Transformation.
[作者:Alberti, Mariza N.;Vassilikogiannakis, Georgios;Orfanopoulos, Michael;,期刊:Organic Letters, 页码:3997-4000 , 文章类型: 研究论文,,卷期:2008年10-18]
- oxygen (1O2), using the optically active alkene (S,S)-cis-1,4-diphenyl-2-butene-1,4-d2, in MeOH and aprotic solvents was investigated. Our findings indicate that the title reaction is a highly stereospecific suprafacial...
- The Coupling of Isonitriles and Carboxylic Acids Occurring By Sequential Concerted Rearrangement Mechanisms.
[作者:Jones, Gavin O.;Li, Xuechen;Hayden, Amy E.;Houk, K. N.;Danishefsky, Samuel J.;,期刊:Organic Letters, 页码:4093-4096 , 文章类型: 研究论文,,卷期:2008年10-18]
- Mechanisms for the recently described reactions of isonitriles with carboxylic acids (Li, X.; Danishefsky, S. J. J. Am. Chem. Soc.2008, 130, 5446) are explored with the B3LYP d. functional method. The mechanism involves...
- Highly Practical Catalytic Asymmetric 1,4-Addition of Arylboronic Acids in Water Using New Hydrophilic Chiral Bicyclo[3.3.0] Diene Ligands.
[作者:Feng, Chen-Guo;Wang, Zhi-Qian;Shao, Cheng;Xu, Ming-Hua;Lin, Guo-Qiang;,期刊:Organic Letters, 页码:4101-4104 , 文章类型: 研究论文,,卷期:2008年10-18]
- The first Rh-diene-catalyzed aq. asym. 1,4-addn. of a,b-unsatd. carbonyl compds. with arylboronic acids has been realized. Using hydrophilic bicyclo[3.3.0] diene ligand I, the reactions can be performed successfully in ...
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