- Formal total synthesis of (-)-physostigmine.
[作者:Asakawa, Kaori;Noguchi, Naoyoshi;Nakada, Masahisa;,期刊:Heterocycles, 页码:183-190 , 文章类型: 研究论文,,卷期:2008年76-1]
- The formal total synthesis of (-)-physostigmine is described via (R)-2-(2-chlorophenyl)-2-(methoxycarbonyl)propanoate (99% ee), newly prepd. by pig liver esterase (PLE) mediated asym. hydrolysis of the corresponding dies...
- Photodimerization of pyrido[2,1-a]isoindol-6(4H)-one.
[作者:Paquette, Leo A.;Dura, Robert D.;Gallucci, Judith C.;,期刊:Heterocycles, 页码:129-132 , 文章类型: 研究论文,,卷期:2008年76-1]
- When subjected to acetone-sensitized irradn., the title compd. V undergoes near-quant. self-coupling to give an uncommon [4+2] dimer VI, whose reaction with several oxidants demonstrated the enamide double bond of the ph...
- Asymmetric synthesis of the ABCD ring system of daphnilactone B via a tandem, double intramolecular, [4+2]/[3+2] cycloaddition strategy.
[作者:Denmark, Scott E.;Nguyen, Son T.;Baiazitov, Ramil Y.;,期刊:Heterocycles, 页码:143-154 , 文章类型: 研究论文,,卷期:2008年76-1]
- An asym. synthesis of the ABCD ring system of daphnilactone B is described. The synthesis features a tandem, double intramol., [4+2]/[3+2] cycloaddn. of a highly functionalized, enantiomerically enriched nitro alkene to...
- Regioselective introduction of electrophiles into piperidine derivatives at the 4-position.
[作者:Onomura, Osamu;Fujimura, Noriyuki;Oda, Takahisa;Matsumura, Yoshihiro;Demizu, Yosuke;,期刊:Heterocycles, 页码:177-182 , 文章类型: 研究论文,,卷期:2008年76-1]
- Regioselective introduction of various electrophiles (aldehydes, ketones, and imines) into piperidine skeleton at the 4-position was achieved with a catalytic amt. of Pd(OAc)2/PPh3 in the presence of excess Et2Zn. In ad...
- Marchantiophyta (liverworts): rich sources of macrocyclic bis(bibenzyls).
[作者:Asakawa, Yoshinori;Toyota, Masao;Hashimoto, Toshihiro;Tori, Motoo;Nagashima, Fumihiro;Harinantenaina, Liva;,期刊:Heterocycles, 页码:99-127 , 文章类型: 研究论文,,卷期:2008年76-1]
- bis(bibenzyls) which show interesting biol. activity such as antimicrobial, antifungal, antiobesity and muscle relaxing activity etc. and are of very valuable for the chemosystematic and evolutionary study of the Marchan...
- Syntheses, structures, and properties of bithiophenophanes bridged at 1,8-positions of naphthalenes.
[作者:Nakao, Kazumi;Nishiuchi, Tomohiko;Iyoda, Masahiko;,期刊:Heterocycles, 页码:727-745 , 文章类型: 研究论文,,卷期:2008年76-1]
- The 2,2'-bithiophenophanes I (R = H, Et) bridged at the 1,8-positions of naphthalenes together with their linear dimers, trimers and a tetramer were synthesized by the homo-coupling of 1,8-di(5-lithio-2-thienyl)naphthale...
- Synthesis, molecular structure, and oxidation behavior of exhaustively methylated azacalix[6]arene.
[作者:Ishibashi, Koichi;Tsue, Hirohito;Takahashi, Hiroki;Tokita, Satoshi;Matsui, Kazuhiro;Tamura, Rui;,期刊:Heterocycles, 页码:541-550 , 文章类型: 研究论文,,卷期:2008年76-1]
- The mol. structure and oxidn. behavior of an exhaustively methylated aza calix[6]arene were investigated with the intention of developing high-spin materials. The aza calix[6]arene adopted a distorted 1,3-alternate conf...
- Facile synthesis of (2-benzimidazolyl)-1-azaazulenes, (2-benzothiazolyl)-1-azaazulenes, and related compounds and evaluation of their anticancer in vitro activity.
[作者:Yamauchi, Noriko;Fujii, Hiroyuki;Kakehi, Akikazu;Shiro, Motoo;Kurosawa, Masaki;Konakahara, Takeo;Abe, Noritaka;,期刊:Heterocycles, 页码:617-634 , 文章类型: 研究论文,,卷期:2008年76-1]
- Facile syntheses of 2-, 3,- and 8-(2-benzimidazolyl)-1-azaazulenes and 2-, 3-, and 8-(2-benzothiazolyl)-1-azaazulenes were achieved by the condensation of corresponding 1-azaazulenecarbaldehydes with o-phenylenediamine a...
- Synthesis of 2,5-diaminopyrazine derivatives via dimerization of 2H-azirin-3-amines.
[作者:Mekhael, Maged K. G.;Linden, Anthony;Heimgartner, Heinz;,期刊:Heterocycles, 页码:689-698 , 文章类型: 研究论文,,卷期:2008年76-1]
- 2-Methyl-3-(methylphenylamino)-2H-azirine (I) was prepd. conveniently by subsequent treatment of N-methyl-N-phenylpropanamide in THF with LDA, (PhO)2POCl (DPPCl), and NaN3 in DMF. In the absence of nucleophiles, the rea...
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