Five mixed-metal mixed-valence Mo/V polyoxoanions, templated by the pyramidal SeO32- heteroanion have been isolated: K10[MoVI12VV10O58(SeO3)8]center dot 18?H2O (1), K7[MoVI11VV5VIV2O52(SeO3)]center dot 31?H2O (2), (NH4)7...
The development of magnetic nanoparticles with multiple functions has been an ever-growing field because of their diverse applications in drug delivery, biosensing, cell labeling, and so on. In this study, a facile metho...
A complex titania nanostructure of monodisperse spiky mesoporous anatase beads composed of anatase nanocrystals with diameters of less than 15 nm in the core and much larger hollow-cone shaped spikes on the surface was f...
Germanium-73 is an extremely challenging nucleus to examine by NMR spectroscopy due to its unfavorable NMR properties. Through the use of an ultrahigh (21.1 T) magnetic field, a systematic study of a series of simple org...
Enantioselective conjugate reduction of a wide range of alpha,beta-unsaturated carboxylic esters was achieved using chiral Ir N,P complexes as hydrogenation catalysts. Depending on the substitution pattern of the substra...
The present study elucidates the factors that govern the spontaneous self-assembly of a family of dimetal [Pt2L4] (L=dithiocarboxylato ligand) complexes. Experimental data show that variables such as temperature, concent...
Graphene nanosheets are successfully applied as an effective platform for the 2D ordering of metal oxide nanoparticles. Mesoporous 2D aggregates of anatase TiO2 nanoparticles are synthesized by the heat treatment of the ...
Various low oxidation state (+2) group 14 element amidohydride adducts, IPr center dot EH(BH3)NHDipp (E=Si or Ge; IPr=[(HCNDipp)2C:], Dipp=2,6-iPr2C6H3), were synthesized. Thermolysis of the reported adducts was investig...
A new stable sterically hindered o-quinone annelated with a 1,2-dithiete ring was prepared by using mild conditions. The skeleton of the compound comprises diolate and dithiolate functions that have the potential to bind...