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  • Enantioselective Formal Synthesis of Palmerolide A
    [作者:PRASAD KAVIRAYANI R; PAWAR AMIT B,期刊:Organic Letters, 页码:4252-4255 , 文章类型: Article,,卷期:2011年13-16]
  • Enantioselective formal synthesis of macrolactone palmerolide A, a polyketide marine natural product, is described. Key strategies in the synthesis include the oxidative furan ring-opening of a chiral furyl carbinol for ...
  • Asymmetric Decarboxylative Allylation of Oxindoles
    [作者:FRANCKEVICIUS VILIUS; CUTHBERTSON JAMES D; PICKWORTH MARK; PUGH DAVID S; TAYLOR RICHARD J K,期刊:Organic Letters, 页码:4264-4267 , 文章类型: Article,,卷期:2011年13-16]
  • An asymmetric decarboxylative palladium-catalyzed allylation of alkyl- and aryl-substituted oxindoles has been developed, enabling the installation of an all-carbon quaternary chiral center at the oxindole 3-position in ...
  • Thermally Induced Cycloadditions of Donor/Acceptor Carbenes
    [作者:OVALLES STEPHANIE R; HANSEN JORN H; DAVIES HUW M L,期刊:Organic Letters, 页码:4284-4287 , 文章类型: Article,,卷期:2011年13-16]
  • The thermal decomposition of aryldiazoacetates and aryldiazoketones in the absence of a catalyst leads to synthetically useful transformations. The thermal reaction of aryldiazoacetates with alkenes generates cyclopropan...
  • Catalytic Migratory Oxidative Coupling of Nitrones
    [作者:HASHIZUME SHOGO; OISAKI KOUNOSUKE; KENAI MOTOMU,期刊:Organic Letters, 页码:4288-4291 , 文章类型: Article,,卷期:2011年13-16]
  • A Cu(I)-catalyzed migratory oxidative coupling between nitrones and heterocycles or a methylamine is described. Selective C-C bond-formation proceeds through cleavage of two C(sp(3))-H bonds concomitant with C=N double b...
  • A Stereoselective Inverting sec-Alkylsulfatase for the Deracemization of sec-Alcohols
    [作者:SCHOBER MARKUS; GADLER PETRA; KNAUS TANJA; KAYER HEIDEMARIE; BIRNERGRUENBERGER RUTH; GUELLY CHRISTIAN; MACHEROUX PETER; WAGNER ULRIKE; FABERT KURT,期刊:Organic Letters, 页码:4296-4299 , 文章类型: Article,,卷期:2011年13-16]
  • A metallo-beta-lactamase-type alkylsulfatase was found to catalyze the enantioselective hydrolysis of sec,alkylsulfates with strict inversion of configuration. This catalytic event, which does not have an analog in chemo...