Several fluorinated 1,3-diaminocyclopentanes, previously reported to be useful RNA structural probes, can be prepared in a diastereoselective manner from a single bicyclic hydrazine precursor, in 3 to 9 steps.
New functionalized phenylpyridine ligands and their derived heteroleptic cyclometalated Ir(III) complexes have been synthesized. The complexes possess a combination of important properties: (i) blue emission, (ii) good p...
New chlorodiols (+/-)-3 and (+/-)-5 are densely functionalized and versatile synthons. They are converted in one step on a gram scale into 2-chlorolactones (+/-)-6 and (+/-)-7 and into 4-hydroxy glycidate esters (+/-)-9 ...