- Mild and Highly Enantioselective Vinylogous Aldol Reaction of Brassard's Diene with Aromatic Aldehydes by Combined Lewis Acid Catalyst
[作者:WANG GUOWEI; ZHAO JINFENG; ZHOU YUHAN; WANG BAOMIN; QU JINGPING,期刊:Journal of Organic Chemistry, 页码:5326-5329 , 文章类型: Article,,卷期:2010年75-15]
- The combined Lewis acid catalytic system, generated from (R)-1,1'-bi-2-naphthol [(R)-BINOL], Ti(O-i-Pr)(4), H2O, and lithium chloride, effectively catalyzed the enantioselective vinylogous aldol reaction of Brassard's di...
- A Versatile Synthesis of Fumaquinone
[作者:PENALOPEZ MIGUEL; MONTSERRAT MARTINEZ M; SARANDESES LUIS A; PEREZ SESTELO JOSE,期刊:Journal of Organic Chemistry, 页码:5337-5339 , 文章类型: Article,,卷期:2010年75-15]
- Fumaquinone, a novel prenylated naphthoquinone antibiotic, was synthetized from ethyl acetoacetate in three steps (58% overall yield). The key step of the synthesis is the construction of the naphthoquinone skeleton by a...
- H-Bonding-Assisted Substituent Effect
[作者:KRYGOWSKI TADEUSZ M; ZACHARAHOREGLAD JOANNA E; PALUSIAK MARCIN,期刊:Journal of Organic Chemistry, 页码:4944-4949 , 文章类型: Article,,卷期:2010年75-15]
- In this paper we investigate the influence of intramolecular noncovalent interaction, i.e., H-bonding and Li-bonding, on the properties of substituents communicating through the resonance (mesomeric) effect in such molec...
- Toward Pyrrolo[2,3-d]pyrimidine Scaffolds
[作者:EL KAIM LAURENT; GRIMAUD LAURENCE; WAGSCHAL SIMON,期刊:Journal of Organic Chemistry, 页码:5343-5346 , 文章类型: Article,,卷期:2010年75-15]
- Herein, we present a new route to highly substituted pyrrolo[2,3-d]pyrimidines featuring a Ugi-Smiles/Sonogashira cascade followed by an efficient base-catalyzed intramolecular cyclization. When formaldehyde is chosen as...
- Total Synthesis of Cryptoacetalide
[作者:ZOU YAN; DEITERS ALEXANDER,期刊:Journal of Organic Chemistry, 页码:5355-5358 , 文章类型: Article,,卷期:2010年75-15]
- We are reporting the first total synthesis of the tetracyclic terpene natural product cryptoacetalide. Key steps of the synthesis are a microwave-mediated [2+2+2] cyclotrimerization reaction to construct the central benz...
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