- Directly Probing Molecular Ordering at the Buried Polymer/Metal Interface
[作者:Lu, XL; Li, DW; Kristalyn, CB; Han, JL; Shephard, N; Rhodes, S; Xue, G; Chen, Z,期刊:Macromolecules, 页码:9052-9057 , 文章类型: Article,,卷期:2009年42-22]
- We developed it methodology to directly probe molecular ordering at the buried polymer/metal interface. Using sum frequency generation (SFG) vibrational spectroscopy, we observed ordering of ester methyl groups at the bu...
- HyperMacs to HyperBlocks: A Novel Class of Branched Thermoplastic Elastomer
[作者:Hutchings, LR; Dodds, JM; Rees, D; Kimani, SM; Wu, JJ; Smith, E,期刊:Macromolecules, 页码:8675-8687 , 文章类型: Article,,卷期:2009年42-22]
- We demonstrate here the great versatility of the macromonomer approach for the synthesis of long chain hyperbranched polymers (HyperMacs) and describe the synthesis of HyperMacs from polybutadiene and poly(methyl methacr...
- Synthesis via RAFT of Amphiphilic Block Copolymers with Liquid-Crystalline Hydrophobic Block and Their Self-Assembly in Water
[作者:Boisse, S; Rieger, J; Di-Cicco, A; Albouy, PA; Bui, C; Li, MH; Charleux, B,期刊:Macromolecules, 页码:8688-8696 , 文章类型: Article,,卷期:2009年42-22]
- Two families of amphiphilic diblock copolymers, in which the hydrophobic block was a cholesteryl-based smectic liquid-crystalline polymer and the hydrophilic block was either a neutral polymer with a lower critical solut...
- Cylindrically Confined Diblock Copolymers
[作者:Dobriyal, P; Xiang, HQ; Kazuyuki, M; Chen, JT; Jinnai, H; Russell, TP,期刊:Macromolecules, 页码:9082-9088 , 文章类型: Article,,卷期:2009年42-22]
- Lamella-, cylinder-, and sphere-forming block copolymers (BCPs) of polystyrene-b-polybutadiene (PS-b-PBD) were drawn into the pores of anodized aluminum oxide (AAO) membranes ill the melt by capillary forces. After therm...
- Synthesis of Soluble Poly(arylene ether sulfone) Ionomers with Pendant Quaternary Ammonium Groups for Anion Exchange Membranes
[作者:Wang, JH; Zhao, Z; Gong, FX; Li, SH; Zhang, SB,期刊:Macromolecules, 页码:8711-8717 , 文章类型: Article,,卷期:2009年42-22]
- A new bisphenol monomer, 2,2'-dimethylaminemetllylene-4,4'-biphenol (DABP), was easily prepared by Mannich reaction of dimethylamine and formaldehyde with 4,4'-biphenol. Novel partially fluorinated poly(arylene ether sul...
- Mechanistic Investigation of the Silane, Germane, and Stannane Behavior When Incorporated in Type I and Type II Photoinitiators of Polymerization in Aerated Media
[作者:El-Roz, M; Lalevee, J; Allonas, X; Fouassier, JP,期刊:Macromolecules, 页码:8725-8732 , 文章类型: Article,,卷期:2009年42-22]
- The role of silanes, germanes, and stannanes R3XH as co-initiators and additives to overcome the oxygen inhibition usually encountered in photopolymerization reactions in aerated media is demonstrated in experimental con...
- Forces of Interaction between Poly(2-vinylpyridine) Brushes As Measured by Optical Tweezers
[作者:Elmahdy, MM; Synytska, A; Drechsler, A; Gutsche, C; Uhlmann, P; Stamm, M; Kremer, F,期刊:Macromolecules, 页码:9096-9102 , 文章类型: Article,,卷期:2009年42-22]
- Forces of interaction within single pairs of poly(2-vinylpyridine) (P2VP) grafted colloids have been measured by optical tweezers (OT) with an extraordinary resolution of +/-0.5 pN. Parameters to be varied are the concen...
- Control of Coalescence in Clusters of Elastomer Colloids through Manipulation of Polymer Composition
[作者:Gauer, C; Wu, H; Morbidelli, M,期刊:Macromolecules, 页码:9103-9110 , 文章类型: Article,,卷期:2009年42-22]
- The effect of rigid polymer content, tetrafluoroethylene (TFE), within elastomer polymer on the coalescence behavior of suspended rubbery particles during fast, diffusion-limited cluster-cluster aggregation (DLCA) has be...
- Reorganizable Chemical Polymer Gels Based on Dynamic Covalent Exchange and Controlled Monomer Insertion
[作者:Amamoto, Y; Kikuchi, M; Masunaga, H; Sasaki, S; Otsuka, H; Takahara, A,期刊:Macromolecules, 页码:8733-8738 , 文章类型: Article,,卷期:2009年42-22]
- Covalently networked polymer gels were developed with two notable functionalities: de-cross-linking by dynamic covalent exchange based on a radical crossover reaction and insertion of a monomer into the cross-linkers. Th...
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