- Efficient and Eco-Friendly Anionic Polymerization of Acrylamide under Microwave Irradiation and Hydrolysis of the Obtained Polymers by Microwave Irradiation
[作者:Iwamura, T; Ashizawa, K; Sakaguchi, M,期刊:Macromolecules, 页码:5001-5006 , 文章类型: Article,,卷期:2009年42-14]
- The polymerization of acrylamide was carried out using t-BuOK as an initiator in DMF under microwave irradiation. As a result, poly(beta-alanine) was obtained in a good yield. With 100 W, 2.45 GHz microwave irradiation, ...
- Mechanical Unfolding of a Homopolymer Globule Studied by Self-Consistent Field Modeling
[作者:Polotsky, AA; Charlaganov, MI; Leermakers, FAM; Daoud, M; Borisov, OV; Birshtein, TM,期刊:Macromolecules, 页码:5360-5371 , 文章类型: Article,,卷期:2009年42-14]
- We present results of numerical self-consistent field (SCF) calculations for the equilibrium mechanical unfolding of a globule formed by a single flexible polymer chain collapsed in a poor solvent. In accordance with ear...
- Synthesis of Well-Defined Poly (ethylene-alt-1-vinyladamantane) via Living Anionic Polymerization of 2-(1-Adamantyl)-1,3-butadiene, Followed by Hydrogenation
[作者:Kobayashi, S; Kataoka, H; Ishizone, T,期刊:Macromolecules, 页码:5017-5026 , 文章类型: Article,,卷期:2009年42-14]
- Anionic polymerization of 2-(1-adamantyl)-1,3-butadiene (1) was carried out either with s-BuLi in cyclohexane at 40 degrees C or with potassium naphthalenide in THF at -78 degrees C. The polymerizations of I quantitative...
- Hyperbranched Azo-Polymers Synthesized by Acyclic Diene Metathesis Polymerization of an AB(2) Monomer
[作者:Ding, L; Zhang, LY; Han, HJ; Huang, W; Song, CM; Xie, MR; Zhang, YQ,期刊:Macromolecules, 页码:5036-5042 , 文章类型: Article,,卷期:2009年42-14]
- A novel hyperbranched azo-polymer was prepared by a ruthenium-based catalyst RuCl2(PCy3)(SIMes)(CHPh) using acyclic diene metathesis (ADMET) polymerization of an AB(2) monomer, 4-undecylenyloxycarbonyl-4'-[bis(2-ethyl ac...
- Dynamics of Semiflexible Chains, Stars, and Dendrimers
[作者:Dolgushev, M; Blumen, A,期刊:Macromolecules, 页码:5378-5387 , 文章类型: Article,,卷期:2009年42-14]
- Focusing on mechanical and dielectric relaxation, we study the dynamics of semiflexible linear chains, stars, and dendrimers. For this, we use an extension of the Rouse-model in which we include, in the spirit of Bixon a...
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