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  • Resonance Energies of Vinylcarbenes.
    [作者:Freeman, Peter K.;,期刊:Journal of Organic Chemistry, 页码:830-833 , 文章类型: 研究论文,,卷期:2009年74-2]
  • The stabilization energy provided by resonance in singlet and triplet vinylcarbenes is evaluated using d. functional and G3 theory, without symmetry restriction. Structural and charge change upon rotation are reviewed w...
  • First Total Synthesis of Cyrmenin B1.
    [作者:Chakor, Narayan S.;Musso, Loana;Dallavalle, Sabrina;,期刊:Journal of Organic Chemistry, 页码:844-849 , 文章类型: 研究论文,,卷期:2009年74-2]
  • A short and efficient synthesis of cyrmenin B1 (I), an antifungal metabolite of myxobacteria Cystobacter armeniaca and Archangium gephyra, is described. The crucial steps of the synthesis included the formation of the d...