- Toward controlled Gilch synthesis of poly(p-phenylene vinylenes): Anionic vs radical chain propagation, a mechanistic reinvestigation
[作者:Schwahn, T; Wiesecke, J; Immel, S; Rehahn, M,期刊:Macromolecules, 页码:8842-8854 , 文章类型: Article,,卷期:2007年40-25]
- It is a broad consensus that the first step in the Gilch synthesis of poly (p-phenylene vinylenes) (PPVs) is 1,6-dehydrohalogenation of the 1,4-bis(halomethylene)benzene starting materials. The mechanism of the subsequen...
- Synthesis, characterization, crystalline morphologies, and hydrophilicity of brush copolymers with double crystallizable side chains
[作者:Yuan, WZ; Yuan, JY; Zhang, FB; Xie, XM; Pan, CY,期刊:Macromolecules, 页码:9094-9102 , 文章类型: Article,,卷期:2007年40-25]
- Novel brush copolymers with poly(2-hydroxyethyl methacrylate) (PHEMA) as polymer backbone and diblock copolymer consisting of crystallizable poly(epsilon-caprolactone) (PCL) and poly(ethylene oxide) (PEO) as side chains ...
- Polypropylene/silicate composites on the basis of crazed polymer and hyperbranched polyethoxysiloxane
[作者:Trofimchuk, ES; Nesterova, EA; Meshkov, IB; Nikonorova, NI; Muzafarov, AM; Bakeev, NP,期刊:Macromolecules, 页码:9111-9115 , 文章类型: Article,,卷期:2007年40-25]
- Hyperbranched polyethoxysiloxane (HPEOS) is suggested as an adsorption-active medium in the crazing of commercial polypropylene film and as a precursor of silica. As a result of delocalized crazing of polypropylene, the ...
- Chemoenzymatic approach toward heterografted molecular bottle brushes
[作者:Hans, M; Keul, H; Heise, A; Moeller, M,期刊:Macromolecules, 页码:8872-8880 , 文章类型: Article,,卷期:2007年40-25]
- Heterografted molecular bottle brushes, i.e., poly(glycidol-graft-epsilon-caprolactone-acetyl)-co-(glycidolgraft-methyl methacrylate) [P(G-graft-CLAC)-co-(G-graft-MMA)] and poly(glycidol-graft-epsilon-caprolactone-acetyl...
- Facile fabrication of reversible core cross-linked micelles possessing thermosensitive swellability
[作者:Zhang, JY; Jiang, X; Zhang, YF; Li, YT; Liu, SY,期刊:Macromolecules, 页码:9125-9132 , 文章类型: Article,,卷期:2007年40-25]
- Poly(ethylene oxide)-b-poly(N-isopropylacrylamide-co-N-acryloxysuccinimide), PEO-b-P(NIPAM-co-NAS), was synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization in dioxane at 70 degrees C em...
- Poly(methyl methacrylate)-poly(caprolactone) AB and ABA block copolymers by combined ring-opening polymerization and atom transfer radical polymerization
[作者:Schappacher, M; Fur, N; Guillaume, SM,期刊:Macromolecules, 页码:8887-8896 , 文章类型: Article,,卷期:2007年40-25]
- Chemical modification of alpha-hydroxy,omega-isopropylestertelechelic iPrO-PCL-OH, 1, and alpha,omega-dihydroxytelechelic HO-PCL-OH, 4, poly(epsilon-caprolactone) (PCL), synthesized from ring-opening polymerization using...
- Mapping poly(butyl acrylate) product distributions by mass Spectrometry in a wide temperature range: Suppression of midchain radical side reactions
[作者:Junkers, T; Koo, SPS; Davis, TP; Stenzel, MH; Barner-Kowollik, C,期刊:Macromolecules, 页码:8906-8912 , 文章类型: Article,,卷期:2007年40-25]
- The polymer product spectra of poly(butyl acrylate), polyBA, samples obtained by full conversion bulk polymerization in the temperature range of 60-140 degrees C in presence of the chain transfer agent (CTA) octylthiol i...
- Synthesis, photophysics, and electroluminescence of copolyfluorenes containing DCM derivatives
[作者:Hsieh, BY; Chen, Y,期刊:Macromolecules, 页码:8913-8923 , 文章类型: Article,,卷期:2007年40-25]
- New copolyfluorenes (PFD0.5-50) of 9,9'-dihexylfluorene and 2-(2,6-bis(4-(2-phenyl-2-cyanovinyl)-2,5-bis(hexyloxy)styryl)-4H-pyran-4-ylidene)malononitrile (DCM) were synthesized by the Suzuki coupling reaction. They were...
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