- Crystallization Kinetics and Crystal Structure of Nylon6-Clay Nanocomposites: Combined Effects of Thermomechanical History, Clay Content, and Cooling Conditions
[作者:Miri, V; Elkoun, S; Peurton, F; Vanmansart, C; Lefebvre, JM; Krawczak, P; Seguela, R,期刊:Macromolecules, 页码:9234-9244 , 文章类型: Article,,卷期:2008年41-23]
- The crystallization behavior and the crystalline structure of nylon6-clay nanocomposites are investigated with regard to the processing conditions and thermal treatment. Microextruded bulk samples as well as blown films ...
- Directed Self-Assembly of Diblock Copolymer Thin Films on Chemically-Patterned Substrates for Defect-Free Nano-Patterning
[作者:Tada, Y; Akasaka, S; Yoshida, H; Hasegawa, H; Dobisz, E; Kercher, D; Takenaka, M,期刊:Macromolecules, 页码:9267-9276 , 文章类型: Article,,卷期:2008年41-23]
- We demonstrate that polystyrene-block-poly(methylmethacrylate) (PS-b-PMMA) can self-assemble in a well-aligned, long-range ordered nanopattern over arbitrarily large areas, commensurate with chemically prepatterned templ...
- Stoichiometric Effects on Nanostructures of Block- and Graft-Type Supramacromolecules via Acid-Base Complexation
[作者:Noro, A; Tamura, A; Wakao, S; Takano, A; Matsushita, Y,期刊:Macromolecules, 页码:9277-9283 , 文章类型: Article,,卷期:2008年41-23]
- We report a systematic study on nanophase-separated structures from block- and graft-type supramacromolecules via acid-base complexation, where supramacromolecules are termed as supramolecules composed of a pair of macro...
- Thin Poly(styrene-block-4-hydroxystyrene) Block Copolymer Films Spin-Coated Directly on Topographic Prepattern Substrates
[作者:Lee, G; Jo, PS; Yoon, BK; Kim, TH; Acharya, H; Ito, H; Kim, HC; Huh, J; Park, CM,期刊:Macromolecules, 页码:9290-9294 , 文章类型: Article,,卷期:2008年41-23]
- We have investigated the formation of as-cast thin films of a poly(styrene-block-4-hydroxystyrene) (PS-b-PHOST) copolymer spin-coated directly on topographic prepattern substrates. Either wetting or dewetting of a polyme...
- Surface Segregation of Counterions in Ionomer Films
[作者:Walters, RM; Taubert, A; Kim, JS; Winey, KI; Composto, RJ,期刊:Macromolecules, 页码:9299-9305 , 文章类型: Article,,卷期:2008年41-23]
- The surface segregation of cations in a poly(styrene-ran-methacrylic acid) ionomer fully neutralized with Cs was demonstrated using Rutherford backscattering spectrometry (RBS), scanning force microscopy (SFM), and scann...
- Evaporative Organization of Hierarchically Structured Polymer Blend Rings
[作者:Byun, M; Hong, SW; Qiu, F; Zou, QZ; Lin, ZQ,期刊:Macromolecules, 页码:9312-9317 , 文章类型: Article,,卷期:2008年41-23]
- We report the first study of the controlled, evaporative self-organization of a polymer blend from a restricted geometry comprised of a spherical lens upon a Si substrate (i.e., a sphere-on-flat geometry). This geometry ...
- A Transition from Cylindrical to Spherical Morphology in Diblock Copolymer Thin Films
[作者:Niihara, KI; Sugimori, H; Matsuwaki, U; Hirato, F; Morita, H; Doi, M; Masunaga, H; Sasaki, S; Jinnai, H,期刊:Macromolecules, 页码:9318-9325 , 文章类型: Article,,卷期:2008年41-23]
- Microphase-separated structures in poly(styrene-block-isoprene) (SI) block copolymer thin films were investigated by transmission electron microtomography (TEMT). The SI block copolymer showed cylindrical microdomains in...
- Dynamic Self-Assembly Induced Rapid Dissolution of Cellulose at Low Temperatures
[作者:Cai, J; Zhang, L; Liu, SL; Liu, YT; Xu, XJ; Chen, XM; Chu, B; Guo, XL; Xu, J; Cheng, H; Han, CC; Kuga, S,期刊:Macromolecules, 页码:9345-9351 , 文章类型: Article,,卷期:2008年41-23]
- Cellulose can be dissolved in precooled (-12 degrees C) 7 wt % NaOH-12 wt % urea aqueous solution within 2 min. This interesting process, to our knowledge, represents the most rapid dissolution of native cellulose. The r...
- Collapse of Linear Polyelectrolyte Chains in a Poor Solvent: When Does a Collapsing Polyelectrolyte Collect its Counterions?
[作者:Loh, P; Deen, GR; Vollmer, D; Fischer, K; Schmidt, M; Kundagrami, A; Muthukumar, M,期刊:Macromolecules, 页码:9352-9358 , 文章类型: Article,,卷期:2008年41-23]
- To better understand the collapse of polyions in poor solvent conditions the effective charge and the solvent quality of the hypothetically uncharged polymer backbone need to be known. In the present work this is achieve...
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