- Facile Synthesis of cis-2-Alkyl-3-trialkylsilyloxycycloalkanones via the Non-Aldol Aldol Rearrangement of 2,3-Epoxycycloalkanols.
[作者:Jung, Michael E.;Allen, Damian A.;,期刊:Organic Letters, 页码:2039-2041 , 文章类型: 研究论文,,卷期:2008年10-10]
- Silyl triflate-promoted rearrangement of cis-2,3-epoxycycloalkanols A, prepd. by epoxidn. of the cyclic allylic alc. and then silylation, afforded good yields (~70-75%) of the cis-2-alkyl-3-silyloxycycloalkanones B, pres...
- Regioselective and Stereospecific Synthesis of Enantiopure 1,3-Oxazolidin-2-ones by Intramolecular Ring Opening of 2-(Boc-aminomethyl)aziridines. Preparation of the Antibiotic Linezolid.
[作者:Moran-Ramallal, Roberto;Liz, Ramon;Gotor, Vicente;,期刊:Organic Letters, 页码:1935-1938 , 文章类型: 研究论文,,卷期:2008年10-10]
- The amide moiety of several enantiopure unactivated 1-aryl- or 1-alkylaziridine-2-carboxamides I [R = Ph, 4-MeC6H4, 4-MeOC6H4, PhCH2, (S)-PhCHMe] were reduced and then N-Boc-protected to afford enantiopure 2-(Boc-aminome...
- Alkenol-alkyne cross metathesis.
[作者:Clark, Daniel A.;Clark, Joseph R.;Diver, Steven T.;,期刊:Organic Letters, 页码:2055-2058 , 文章类型: 研究论文,,卷期:2008年10-10]
- Allyl alcs. and their homologs were used in the enyne cross metathesis to prep. hydroxy-functionalized dienes. Thus, reaction of PhCO2CH2CYCH with HOCH2CH:CH2 in ClCH2CH2Cl contg. Grubbs' second generation catalyst at 8...
- New, General, and Practical Preparation of Methyl Ketones via the Direct Coupling of Amides with CH2Cl2 Promoted by TiCl4/Mg.
[作者:Lin, Kuo-Wei;Tsai, Chi-Hui;Hsieh, I.-Lin;Yan, Tu-Hsin;,期刊:Organic Letters, 页码:1927-1930 , 文章类型: 研究论文,,卷期:2008年10-10]
- The direct coupling of a variety of amides with CH2Cl2 or CD2Cl2 promoted by TiCl4/Mg/THF provides an extremely simple, practical, selective, and efficient approach for the construction of Me ketones. The efficiency and ...
- Unexpected Photooxidation of H-Bonded Tetracene.
[作者:Liang, Zhixiong;Zhao, Wei;Wang, Shenglong;Tang, Qin;Lam, Sheung-Chuen;Miao, Qian;,期刊:Organic Letters, 页码:2007-2010 , 文章类型: 研究论文,,卷期:2008年10-10]
- In our attempts of tuning the mol. packing of tetracene with H-bonding, we found that tetracenediamide was much more vulnerable to photooxidn. than tetracene in crystals despite their similar sensitivity to photooxidn. i...
- Palladium-catalyzed carbene insertion and trapping with carbon nucleophiles.
[作者:Devine, Sean K. J.;Van Vranken, David L.;,期刊:Organic Letters, 页码:1909-1911 , 文章类型: 研究论文,,卷期:2008年10-10]
- Three-component coupling of vinyl halides RCH:CHX (X = Br, I), stabilized carbon nucleophiles (Nu) and diazomethyl silane N2CHSiMe3, catalyzed by Pd(0) complexes, gave vinylsilanes RCH(Nu)CH:CHSiMe3 with high yields. Re...
- Clar-Kekule Structuring in Armchair Carbon Nanotubes.
[作者:Martin-Martinez, Francisco J.;Melchor, Santiago;Dobado, Jose A.;,期刊:Organic Letters, 页码:1991-1994 , 文章类型: 研究论文,,卷期:2008年10-10]
- Geometrical patterns on armchair nanotubes and their dependence on length (up to 10 nm) have been studied using first-principles methods. The results indicate that finite nanotubes do not show a uniform bond structure. ...
- LDA-Mediated Selective Addition Reaction of Vinylidenecyclopropanes with Aldehydes, Ketones, and Enones: Facile Synthesis of Vinylcyclopropenes, Allenols, and 1,3-Enynes.
[作者:Lu, Jian-Mei;Shi, Min;,期刊:Organic Letters, 页码:1943-1946 , 文章类型: 研究论文,,卷期:2008年10-10]
- Highly selective addn. reaction of vinylidenecyclopropanes was realized by treatment with LDA in THF and quenching with aldehydes, ketones, and enones. A no. of vinylcyclopropenes, allenols, and 1,3-enynes were obtained...
- First Total Synthesis of Cassiarin A, a Naturally Occurring Potent Antiplasmodial Alkaloid.
[作者:Rudyanto, Marcellino;Tomizawa, Yuichiro;Morita, Hiroshi;Honda, Toshio;,期刊:Organic Letters, 页码:1921-1922 , 文章类型: 研究论文,,卷期:2008年10-10]
- The first total synthesis of cassiarin A (I), an antiplasmodial alkaloid isolated from Cassia siamea, was achieved via sequential alkynylation of arenes with Sonogashira coupling and 6-endo-dig-cyclization of phenolic ox...
- A Facile Preparation of Imidazolinium Chlorides.
[作者:Kuhn, Kevin M.;Grubbs, Robert H.;,期刊:Organic Letters, 页码:2075-2077 , 文章类型: 研究论文,,卷期:2008年10-10]
- A process for the prepn. of sym. and unsym. imidazolinium chlorides that involves reaction of a formamidine with dichloroethane and a base (a) is described. This method makes it possible to obtain numerous imidazolinium...
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