- A Cyclotrimerization Route to Cannabinoids.
[作者:Teske, Jesse A.;Deiters, Alexander;,期刊:Organic Letters, 页码:2195-2198 , 文章类型: 研究论文,,卷期:2008年10-11]
- Three members of the cannabinoid class, cannabinol I (R = H), cannabinol Me ether I (R = Me), and cannabinodiol II, were synthesized using a microwave-mediated [2 + 2 + 2] cyclotrimerization reaction as the key step. Th...
- Catalytic Enantioselective Addition of Diorganozinc Reagents to Vinyl Sulfones.
[作者:Desrosiers, Jean-Nicolas;Bechara, William S.;Charette, Andre B.;,期刊:Organic Letters, 页码:2315-2318 , 文章类型: 研究论文,,卷期:2008年10-11]
- An efficient method for the catalytic asym. conjugate addn. of diorganozinc reagents to vinyl sulfones (E)-RCH:CHSO2Py (R = Me, Me2CH, Ph, 4-MeOC6H4, 4-F3CC6H4, 2-naphthyl; Py = 2-pyridyl) is reported. Using a Binap稢u c...
- Low Temperature Organocopper-Mediated Two-Component Cross Coupling/Cycloisomerization Approach Toward N-Fused Heterocycles.
[作者:Chernyak, Dmitri;Gadamsetty, Surendra Babu;Gevorgyan, Vladimir;,期刊:Organic Letters, 页码:2307-2310 , 文章类型: 研究论文,,卷期:2008年10-11]
- Organocopper reagents R1Cu(CN)Li (R1 = Me, n-Bu, s-Bu, t-Bu, n-hexyl) or PhCu smoothly react with heterocyclic propargyl mesylates, e.g. I (R2 = H, Me; R3 = H, Me, n-pentyl, Ph, 4-ClC6H4, 4-MeO2CC6H4, etc.) generated in ...
- Novel N-Phosphonio Imine-Catalyzed Epoxidation Reactions.
[作者:Prieur, David;El Kazzi, Aimee;Kato, Tsuyoshi;Gornitzka, Heinz;Baceiredo, Antoine;,期刊:Organic Letters, 页码:2291-2294 , 文章类型: 研究论文,,卷期:2008年10-11]
- A new type of acyclic N-phosphonio imine catalyst for selective epoxidns. has been synthesized. The activity of these imine catalysts can easily be modulated by varying its substituents. The substituent attached to the...
- Stereoselective Alkylidenation of Ketones with 2-(p-Toluenesulfinyl)benzyl Iodide: Synthesis of Enantiomerically Pure Trisubstituted Epoxides.
[作者:Arroyo, Yolanda;Meana, Angela;Sanz-Tejedor, M. Ascension;Garcia Ruano, Jose Luis;,期刊:Organic Letters, 页码:2151-2154 , 文章类型: 研究论文,,卷期:2008年10-11]
- Alkylidenation of arylmethyl, dialkyl, and cyclic ketones with 2-(p-toluenesulfinyl)benzyl iodide in the presence of NaN(SiMe3)2 takes place with a high or complete control of the facial selectivity at the carbonyl group...
- Twofold C-H Functionalization: Palladium-Catalyzed Ortho Arylation of Anilides.
[作者:Brasche, Gordon;Garcia-Fortanet, Jorge;Buchwald, Stephen L.;,期刊:Organic Letters, 页码:2207-2210 , 文章类型: 研究论文,,卷期:2008年10-11]
- The ortho arylation of anilides R1C6H4NHR (R = Ac, R1 = 2-Me; R = pivaloyl, R1 = 3-Me, 2,3-Me2, 2-Me-4-MeO, etc.) to form biphenyls, e.g. I (R = 3-Me, 2-Me-4-MeO, 3-F, 2-F-4-Me), via a twofold C-H functionalization/C-C b...
- Asymmetric Total Synthesis of Antiochic Acid.
[作者:Zhao, Yu-Jun;Loh, Teck-Peng;,期刊:Organic Letters, 页码:2143-2145 , 文章类型: 研究论文,,卷期:2008年10-11]
- The first asym. total synthesis of antiochic acid I using bioinspired polyene cyclization strategy is described. Reacting polyene II with acetal III gave tricyclic product IV which was transformed into I. Both good yie...
- Microwave-Accelerated Competing Domino Processes: A Tether-Controlled Dual Pathway into High Molecular Complexity.
[作者:Elkhayat, Zobida;Safir, Imad;Castellote, Isabel;Retailleau, Pascal;Arseniyadis, Simeon;,期刊:Organic Letters, 页码:2219-2222 , 文章类型: 研究论文,,卷期:2008年10-11]
- Bicyclic unsatd. diols undergo a path selective modular domino transformation upon subjection to Pb(OAc)4, the reaction being biased to the nature of the angular substituent. The magnitude of the linking chain and the n...
- General, Robust, and Stereocomplementary Preparation of b-Ketoester Enol Tosylates as Cross-Coupling Partners Utilizing TsCl - N-Methylimidazole Agents.
[作者:Nakatsuji, Hidefumi;Ueno, Kanako;Misaki, Tomonori;Tanabe, Yoo;,期刊:Organic Letters, 页码:2131-2134 , 文章类型: 研究论文,,卷期:2008年10-11]
- A general, robust, and cost-effective method for the (E)- or (Z)-stereocomplementary enol tosylation of b-ketoesters using TsCl-N-methylimidazole (NMI)-Et3N or LiOH has been developed. TsCl coupled with NMI formed a hig...
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