- Water-Mediated Catalyst Preactivation: An Efficient Protocol for C-N Cross-Coupling Reactions.
[作者:Fors, Brett P.;Krattiger, Philipp;Strieter, Eric;Buchwald, Stephen L.;,期刊:Organic Letters, 页码:3505-3508 , 文章类型: 研究论文,,卷期:2008年10-16]
- Derivatives, and Condensed Benzenoid Compounds) Section A protocol for forming a highly active Pd(0) catalyst from Pd(OAc)2, water, and biaryldialkylphosphine ligands has been developed. This protocol generates a cataly...
- A Highly Diastereo- and Enantioselective Synthesis of Multisubstituted Cyclopentanes with Four Chiral Carbons by the Organocatalytic Domino Michael-Henry Reaction.
[作者:Tan, Bin;Chua, Pei Juan;Zeng, Xiaofei;Lu, Min;Zhong, Guofu;,期刊:Organic Letters, 页码:3489-3492 , 文章类型: 研究论文,,卷期:2008年10-16]
- Highly functionalized cyclopentanes with four stereogenic carbons including two quaternary stereocenters, e.g. I (R = Ph, 3-MeOC6H4, 4-BrC6H4, 2-thienyl, 2-furyl, 1-naphthyl, etc.), have been synthesized in excellent yie...
- Controllable Highly Stereoselective Reaction of in situ Generated Magnesium Dienolate Intermediates with Different Electrophiles.
[作者:Lu, Zhan;Chai, Guobi;Zhang, Xiaobing;Ma, Shengming;,期刊:Organic Letters, 页码:3517-3520 , 文章类型: 研究论文,,卷期:2008年10-16]
- An efficient controllable stereoselective a-acylation and -allylation reactions of the magnesium dienolate intermediates, generated in situ by the Fe(III)-catalyzed reaction of allenoates R1CH:C:CR2CO2Et (R1 = Ph, 4-FC6H...
- Novel N,N,P-Tridentate Ligands for the Highly Enantioselective Copper-Catalyzed 1,4-Addition of Dialkylzincs to Enones.
[作者:Kawamura, Kenjiro;Fukuzawa, Hitomi;Hayashi, Masahiko;,期刊:Organic Letters, 页码:3509-3512 , 文章类型: 研究论文,,卷期:2008年10-16]
- (S)-QuCH:NCHRCH2PPh2 (Qu = 2-quinolyl) and 0.1 mol % of Cu(OTf)2 enabled the enantioselective 1,4-addn. of dialkylzincs to cyclic enones to produce 1,4-adducts in up to 99% ee.
- Brevisamide: an unprecedented monocyclic ether alkaloid from the dinoflagellate Karenia brevis that provides a potential model for ladder-frame initiation.
[作者:Satake, Masayuki;Bourdelais, Andrea J.;Van Wagoner, Ryan M.;Baden, Daniel G.;Wright, Jeffrey L. C.;,期刊:Organic Letters, 页码:3465-3468 , 文章类型: 研究论文,,卷期:2008年10-16]
- K. brevis is known for the prodn. of brevetoxins, a family of polycyclic ether toxins, as well as their antagonist brevenal. Further examn. of org. exts. of K. brevis has uncovered yet another unprecedented cyclic ether...
- Cladoniamides A-G, tryptophan-derived alkaloids produced in culture by Streptomyces uncialis.
[作者:Williams, David E.;Davies, Julian;Patrick, Brian O.;Bottriell, Helen;Tarling, Tamsin;Roberge, Michel;Andersen, Raymond J.;,期刊:Organic Letters, 页码:3501-3504 , 文章类型: 研究论文,,卷期:2008年10-16]
- Cladoniamides A-G were isolated from cultures of S. uncialis, and their structures were elucidated by a combination of spectroscopic anal. and an X-ray diffraction anal. of cladoniamide A (I). The cladoniamides have unp...
- Sporulenes, heptaprenyl metabolites from Bacillus subtilis spores.
[作者:Kontnik, Renee;Bosak, Tanja;Butcher, Rebecca A.;Brocks, Jochen J.;Losick, Richard;Clardy, Jon;Pearson, Ann;,期刊:Organic Letters, 页码:3551-3554 , 文章类型: 研究论文,,卷期:2008年10-16]
- Sporulene, a C35-terpenoid hydrocarbon with an unusual pentacyclic structure, is produced by B. subtilis during sporulation.
- Bidirectional switching of near IR emitting boradiazaindacene fluorophores.
[作者:Deniz, Erhan;Isbasar, G. Ceyda;Bozdemir, O. Altan;Yildirim, Leyla T.;Siemiarczuk, Aleksander;Akkaya, Engin U.;,期刊:Organic Letters, 页码:3401-3403 , 文章类型: 研究论文,,卷期:2008年10-16]
- 73, 75, 78 Two novel distyryl-boradiazaindacene dyes with dimethylaminostyryl and pyridylethenyl substituents display opposite spectral shifts on protonation with TFA in org. solvents. This bidirectional switching of th...
- Total Synthesis of (?-2-O-Methylneovibsanin H.
[作者:Chen, Annette P.-J.;Williams, Craig M.;,期刊:Organic Letters, 页码:3441-3443 , 文章类型: 研究论文,,卷期:2008年10-16]
- The total synthesis of (?-2-O-methylneovibsanin H (I) was achieved in 12 steps. An acid-catalyzed, one-pot, four-step cascade reaction was key to the concise total synthesis, lending support to the proposed biosynthesis...
- A Concise Total Synthesis of Largazole, Solution Structure, and Some Preliminary Structure Activity Relationships.
[作者:Nasveschuk, Christopher G.;Ungermannova, Dana;Liu, Xuedong;Phillips, Andrew J.;,期刊:Organic Letters, 页码:3595-3598 , 文章类型: 研究论文,,卷期:2008年10-16]
- A total synthesis of largazole (I) that proceeds in 8 steps from com. materials is reported, along with some structure-activity relationships. A combination of NMR studies and mol. modeling have also provided a prelimina...
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