- Calcium-Catalyzed Pictet-Spengler Reactions.
[作者:Vanden Eynden, Matthew J.;Stambuli, James P.;,期刊:Organic Letters, 页码:5289-5291 , 文章类型: 研究论文,,卷期:2008年10-22]
- Pictet-Spengler reactions of m-tyramine and aldehydes produced tetrahydroisoquinolines, e.g., I, in the presence of a catalytic amt. of Ca[OCH(CF3)2]2. This reaction occurs with a variety of aryl, heteroaryl, and alkyl ...
- Sustainable Synthetic Methods: Domino Construction of Dihydropyridin-4-ones and b-Amino Esters in Aqueous Ethanol.
[作者:Alaimo, Peter J.;O'Brien, Robert, III;Johnson, Adam W.;Slauson, Sarah R.;O'Brien, Jeannette M.;Tyson, Elizabeth L.;Marshall, Amanda-Lynn;Ottinger, Colleen E.;Chacon, Jon G.;Wallace, Lorien;Paulino, Corey Y.;Connell, Sarah;,期刊:Organic Letters, 页码:5111-5114 , 文章类型: 研究论文,,卷期:2008年10-22]
- Domino reactions were designed to allow the byproduct of an upstream reaction to be internally recycled to catalyze a downstream reaction in a one-pot tandem sequence. Nitroarene redn. by In generates an amine and InIII...
- Bismuth-Catalyzed Intramolecular Carbo-oxycarbonylation of 3-Alkynyl Esters.
[作者:Komeyama, Kimihiro;Takahashi, Keita;Takaki, Ken;,期刊:Organic Letters, 页码:5119-5122 , 文章类型: 研究论文,,卷期:2008年10-22]
- Borderline metal complexes, esp. Bi(OTf)3, efficiently catalyze the carbo-oxycarbonylation of alkynyl esters to form multisubstituted lactones, e.g., I, in moderate to high yields.
- Au-Catalyzed Synthesis of 5,6-Dihydro-8H-indolizin-7-ones from N-(Pent-2-en-4-ynyl)-b-lactams.
[作者:Peng, Yu;Yu, Meng;Zhang, Liming;,期刊:Organic Letters, 页码:5187-5190 , 文章类型: 研究论文,,卷期:2008年10-22]
- Au-catalyzed synthesis of 5,6-dihydro-8H-indolizin-7-ones, e.g, I, from readily available N-(pent-2-en-4-ynyl)-b-lactams is developed. In this reaction, a 5-exo-dig cyclization of the b-lactam nitrogen to the Au-activat...
- Diastereoselective Palladium-Catalyzed a-Arylation of 4-Substituted Cyclohexyl Esters.
[作者:Bercot, Eric A.;Caille, Seb;Bostick, Tracy M.;Ranganathan, Krishnakumar;Jensen, Randy;Faul, Margaret M.;,期刊:Organic Letters, 页码:5251-5254 , 文章类型: 研究论文,,卷期:2008年10-22]
- cyclohexyl esters has been developed. The reaction proceeds at room temp. in the presence of [(t-Bu3P)PdBr]2 providing products in up to 37:1 dr.
- Diazatetraester 1H-Pyrazole Crowns as Fluorescent Chemosensors for AMPH, METH, MDMA (Ecstasy), and Dopamine.
[作者:Reviriego, Felipe;Navarro, Pilar;Garcia-Espana, Enrique;Albelda, M. Teresa;Frias, Juan C.;Domenech, Antonio;Yunta, Maria J. R.;Costa, Ruben;Orti, Enrique;,期刊:Organic Letters, 页码:5099-5102 , 文章类型: 研究论文,,卷期:2008年10-22]
- The synthesis and steady-state fluorescence studies on the interaction with AMPH, METH, MDMA, and DA of two diazatetraester pyrazole functions, in a water/ethanol 70:30 mixt. at physiol. pH, are described.
- Hg2+ Selective Fluorescent and Colorimetric Sensor: Its Crystal Structure and Application to Bioimaging.
[作者:Chen, Xiaoqiang;Nam, Seong-Won;Jou, Min Jung;Kim, Youngmee;Kim, Sung-Jin;Park, Sungsu;Yoon, Juyoung;,期刊:Organic Letters, 页码:5235-5238 , 文章类型: 研究论文,,卷期:2008年10-22]
- A Hg2+-selective rhodamine 6G deriv. bearing thiolactone moiety was synthesized, and its crystal structure with Hg2+ is presented to explain the binding mode. In addn., highly selective "off-on"-type fluorescent change ...
- Rapid enantiomeric excess and concentration determination using simple racemic metal complexes.
[作者:Nieto, Sonia;Lynch, Vincent M.;Anslyn, Eric V.;Kim, Hyunwoo;Chin, Jik;,期刊:Organic Letters, 页码:5167-5170 , 文章类型: 研究论文,,卷期:2008年10-22]
- Racemic-metal complexes were used to det. identity, enantiomeric excess, and concn. of chiral diamines using metal-to-ligand charge transfer bands in CD spectroscopy. It takes under just 2 min per sample to det. [G]t an...
- A 1,8-Naphthyridine-Based Fluorescent Chemodosimeter for the Rapid Detection of Zn2+ and Cu2+.
[作者:Yu, Ming-Ming;Li, Zhan-Xian;Wei, Liu-He;Wei, Dong-Hui;Tang, Ming-Sheng;,期刊:Organic Letters, 页码:5115-5118 , 文章类型: 研究论文,,卷期:2008年10-22]
- A novel fluorescent chemodosimeter based on 1,8-naphthyridine exhibits high selectivity to Zn2+ and Cu2+. When 1-(7-acetamino-1,8-naphthyridyl)-2-(6-diacetaminopyridyl)ethene was mixed with CuCl2, hydrolysis of the acet...
- Tailoring b-Cyclodextrin for DNA Complexation and Delivery by Homogeneous Functionalization at the Secondary Face.
[作者:Ortega-Caballero, Fernando;Ortiz Mellet, Carmen;Le Gourrierec, Loic;Guilloteau, Nicolas;Di Giorgio, Christophe;Vierling, Pierre;Defaye, Jacques;Garcia Fernandez, Jose M.;,期刊:Organic Letters, 页码:5143-5146 , 文章类型: 研究论文,,卷期:2008年10-22]
- An efficient general strategy for the incorporation of functional elements onto the secondary hydroxyl rim of b-cyclodextrin has been developed and applied to the synthesis of a novel series of C7-sym. homogeneous macrom...
- Switch peptide via Staudinger reaction.
[作者:Nepomniaschiy, Natalia;Grimminger, Valerie;Cohen, Aviv;DiGiovanni, Saviana;Lashuel, Hilal A.;Brik, Ashraf;,期刊:Organic Letters, 页码:5243-5246 , 文章类型: 研究论文,,卷期:2008年10-22]
- A new transformation based on the Staudinger reaction is described, and its application in the design of a novel switch element to control peptide folding is demonstrated. We found that the azide switch is activated rap...
- An Ireland-Claisen approach to b-alkoxy a-amino acids.
[作者:Tellam, James P.;Kociok-Kohn, Gabriele;Carbery, David R.;,期刊:Organic Letters, 页码:5199-5202 , 文章类型: 研究论文,,卷期:2008年10-22]
- A diastereoselective Ireland-Claisen approach to b-alkoxy a-amino acid esters is reported. Amino acid esters of enol ethereal allylic alcs. undergo facile syn-selective [3,3]-sigmatropic rearrangement via silyl ketene a...
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