- Tandem Friedel-Crafts annulation to novel perylene analogues.
[作者:Penick, Mark A.;Mahindaratne, Mathew P. D.;Gutierrez, Robert D.;Smith, Terrill D.;Tiekink, Edward R. T.;Negrete, George R.;,期刊:Journal of Organic Chemistry, 页码:6378-6381 , 文章类型: 研究论文,,卷期:2008年73-16]
- Novel dialkyloxy- and dihydroxyoctahydroperylenes are regioselectively available via a tandem Friedel-Crafts alkylation of tetrahydronaphthalene precursors followed by oxidative aromatization. Heating of 5-alkyloxy-1-tet...
- Aromatic Nitration in Liquid Ag0.51K0.42Na0.07NO3.
[作者:Mascal, Mark;Yin, Lunxiang;Edwards, Ross;Jarosh, Michael;,期刊:Journal of Organic Chemistry, 页码:6148-6151 , 文章类型: 研究论文,,卷期:2008年73-16]
- Arom. mols. have a strong affinity for silver(I) and dissolve to a limited extent in Ag0.51K0.42Na0.07NO3, a low-melting eutectic mixt. of silver, potassium, and sodium nitrates. Arom. nitration in this inorg. ionic liq...
- 1,5-Asymmetric Induction in Boron-Mediated Aldol Reactions of b-Alkoxy Methylketones.
[作者:Dias, Luiz C.;de Marchi, Anderson A.;Ferreira, Marco A. B.;Aguilar, Andrea M.;,期刊:Journal of Organic Chemistry, 页码:6299-6311 , 文章类型: 研究论文,,卷期:2008年73-16]
- Good levels of substrate-controlled, 1,5-syn-stereoinduction are obtained in boron-mediated aldol reactions of b-trichloromethyl-b-alkoxy and b-trifluoromethyl-b-alkoxy methylketones X3CCH(OR1)CH2COMe (R1 = PhCH2, Me3CSi...
- Diastereoselective Synthesis of Useful Building Blocks by Crotylation of b-Branched a-Methylaldehydes with Potassium Crotyltrifluoroborates.
[作者:Tanaka, Kyosuke;Fujimori, Yukiko;Saikawa, Yoko;Nakata, Masaya;,期刊:Journal of Organic Chemistry, 页码:6292-6298 , 文章类型: 研究论文,,卷期:2008年73-16]
- The diastereoselective construction of stereotriads having consecutive Me, hydroxy, and Me substituents was realized by the substrate-controlled crotylation of b-branched a-methylaldehydes with potassium crotyltrifluorob...
- Asymmetric Addition of Dimethylzinc to a-Ketoesters Catalyzed by (-)-MITH.
[作者:Wu, Hsyueh-Liang;Wu, Ping-Yu;Shen, Ying-Ying;Uang, Biing-Jiun;,期刊:Journal of Organic Chemistry, 页码:6445-6447 , 文章类型: 研究论文,,卷期:2008年73-16]
- This investigation describes the catalytic asym. addn. of dimethylzinc to a-ketoesters ArCOCO2R (Ar = Ph, R = Me, Et, iso-Pr, tert-Bu; Ar = and tri-Et borate as an additive to give the corresponding chiral a-hydroxy este...
- Copper-Mediated N-Cyclopropylation of Azoles, Amides, and Sulfonamides by Cyclopropylboronic Acid.
[作者:Benard, Sebastien;Neuville, Luc;Zhu, Jieping;,期刊:Journal of Organic Chemistry, 页码:6441-6444 , 文章类型: 研究论文,,卷期:2008年73-16]
- The reaction of azoles, amides, and sulfonamides in dichloroethane with readily available cyclopropylboronic acid in the presence of copper acetate and sodium carbonate afforded the N-cyclopropyl derivs. in good to excel...
- Enantioselective BINOL-phosphoric acid catalyzed Pictet-Spengler reactions of N-benzyltryptamine.
[作者:Sewgobind, Nishant V.;Wanner, Martin J.;Ingemann, Steen;de Gelder, Rene;van Maarseveen, Jan H.;Hiemstra, Henk;,期刊:Journal of Organic Chemistry, 页码:6405-6408 , 文章类型: 研究论文,,卷期:2008年73-16]
- Optically active tetrahydro-b-carbolines were synthesized via an (R)-BINOL-phosphoric acid-catalyzed asym. Pictet-Spengler reaction of N-benzyltryptamine with a series of arom. and aliph. aldehydes. The tetrahydro-b-car...
- Total syntheses of (?-crinine, (?-crinamine, and (?-6a-epi-crinamine via the regioselective synthesis and Diels-Alder reaction of 3-aryl-5-bromo-2-pyrone.
[作者:Nguyen, Thanh Tam;Chang, Jayhyok;Jung, Eun-Ju;Cho, Cheon-Gyu;,期刊:Journal of Organic Chemistry, 页码:6258-6264 , 文章类型: 研究论文,,卷期:2008年73-16]
- We have devised a new unified synthetic protocol to (?-crinine (I), (?-crinamine (II), and (?-6a-epi-crinamine from the Diels-Alder cycloadduct of 3-(3,4-methylenedioxyphenyl)-5-bromo-2-pyrone with TBS vinyl ether. The ...
- Synthesis of Fullerooxazoles: Novel Reactions of [60]Fullerene with Nitriles Promoted by Ferric Perchlorate.
[作者:Li, Fa-Bao;Liu, Tong-Xin;Wang, Guan-Wu;,期刊:Journal of Organic Chemistry, 页码:6417-6420 , 文章类型: 研究论文,,卷期:2008年73-16]
- (Heterocyclic Compounds (More Than One Hetero Atom)) Section The ferric perchlorate-mediated reactions of C60 with various nitriles RCN (R = EtO2CCH2, Ph, 4-MeC6H4, 4-O2NC6H4, PhCH2, etc.) in o-dichlorobenzene under nitr...
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