- Synthesis of 1,2,4-trisubstituted imidazoles and 1,3,5-trisubstituted 1,2,4-triazoles.
[作者:Baumgartner, Corinne;Brandli, Lukas;Diederich, Francois;,期刊:Heterocycles, 页码:401-428 , 文章类型: 研究论文,,卷期:2008年76-1]
- Synthetic strategies are reported to easily access 1,2,4-trisubstituted followed by substitution at N(1). Furthermore, a synthesis of trisubstituted 1,2,4-triazoles via a cyclization of hydrazonamides is described.
- Efficient preparation of 2-imidazolines from aldehydes and ethylenediamines with 1,3-diiodo-5,5-dimethylhydantoin.
[作者:Takahashi, Shogo;Togo, Hideo;,期刊:Heterocycles, 页码:507-514 , 文章类型: 研究论文,,卷期:2008年76-1]
- Various 2-imidazolines were prepd. in high yields by reacting aldehydes and ethylenediamines with 1,3-diiodo-5,5-dimethylhydantoin. Moreover, chiral 1,3-diimidazolin-2-ylbenzene and 2,6-diimidazolin-2-ylpyridines, which...
- Preparation of new nitrogen-bridged heterocycles. Part 63.
[作者:Unexpected formation of thieno[3',4':4,5]imidazo[1,2-a]pyridines. Kakehi, Akikazu;Suga, Hiroyuki;Izumita, Atsushi;Abe, Takashi;,期刊:Heterocycles, 页码:391-399 , 文章类型: 研究论文,,卷期:2008年76-1]
- The alk. treatment and dehydrogenation of pyridinium salts, obtainable from the S-alkylation of 3,5-dimethylpyridinium 2-alkylthio-1-cyano-2-thioxoethylides with phenacyl bromides, afforded unexpected heterocycles, 3-alk...
- Chiral cationic Pd-phosphinooxazolidine catalysts for a highly efficient asymmetric Diels-Alder reaction in ionic liquids.
[作者:Nakano, Hiroto;Nishiuchi, Yasuhiro;Takahashi, Kouichi;Fujita, Reiko;Uwai, Koji;Takeshita, Mitsuhiro;,期刊:Heterocycles, 页码:381-390 , 文章类型: 研究论文,,卷期:2008年76-1]
- Chiral cationic palladium-phosphinooxazolidine catalysts in ionic liq. afforded good to excellent enantioselectivity in Diels-Alder reactions of cyclic and acyclic 1,3-dienes with N-acryloyl-2-oxazolidinones. The cataly...
- Silver-catalyzed synthesis of 1,2-dihydroisoquinolines through direct addition of carbon pronucleophiles to ortho-alkynylaryl aldimines.
[作者:Asao, Naoki;Salprima, Yudha S.;Nogami, Tsutomu;Yamamoto, Yoshinori;,期刊:Heterocycles, 页码:471-483 , 文章类型: 研究论文,,卷期:2008年76-1]
- AgOTf-catalyzed reaction of 2-alkynyl-aryl aldimines with various kinds of pro-nucleophiles afforded a variety of 1,2-dihydroisoquinolines in good to high yields. Treatment of 2-alkynyl-aryl aldimines with a stoichiomet...
- Enantiomeric resolution of racemic C2-symmetric trans-2,5-dimethyl-2,5-diphenylpyrrolidine and trans-2,5-dimethyl-2,5-bis(3-hydroxyphenyl)pyrrolidine by a diastereomer method.
[作者:Uchida, Yoshiaki;Nakayama, Yoichi;Suzuki, Katsuaki;Oki, Shigeaki;Horiguchi, Masahiro;Tsue, Hirohito;Tamura, Rui;,期刊:Heterocycles, 页码:875-881 , 文章类型: 研究论文,,卷期:2008年76-1]
- The racemic samples of C2-sym. trans-2,5-dimethyl-2,5-diphenylpyrrolidine (I, R = H) and trans-2,5-dimethyl-2,5-bis(3-hydroxyphenyl)pyrrolidine (I, R = OH) have been resolved by the diastereomer method using D- or L-tart...
- A facile and efficient synthesis of mono- and bis-functionalized meso-substituted porphyrins via palladium-catalyzed Negishi cross-coupling.
[作者:Takanami, Toshikatsu;Yotsukura, Miku;Inoue, Wakaba;Inoue, Naoyuki;Hino, Fumio;Suda, Kohji;,期刊:Heterocycles, 页码:439-453 , 文章类型: 研究论文,,卷期:2008年76-1]
- A series of mono- and bis-functionalized meso-substituted porphyrins bearing chem. reactive functional groups such as CO2R, Cl, and CN in the alkyl substituents at the meso positions were efficiently synthesized by the r...
- Total synthesis of an endothelin converting enzyme inhibitor, TMC-66.
[作者:Hosokawa, Seijiro;Fumiyama, Hitoshi;Fukuda, Hisato;Fukuda, Tomohiro;Seki, Masashi;Tatsuta, Kuniaki;,期刊:Heterocycles, 页码:699-713 , 文章类型: 研究论文,,卷期:2008年76-1]
- The first total synthesis and structural detn. of TMC-66, an ECE inhibitor, was achieved in short steps by efficient construction of two tricyclic segments and coupling reactions. The intramol. oxidative coupling with p...
- The octaethylporphyrin-dihexylbithiophene derivatives combined with pyridine and pyrimidine rings. Their syntheses and proton-mediated and heat-driven spectral changes.
[作者:Higuchi, Hiroyuki;Hayashi, Naoto;Matsukihira, Takuya;Kawakami, Takanori;Takizawa, Toru;Saito, Junji;Miyabayashi, Keiko;Miyake, Mikio;,期刊:Heterocycles, 页码:353-380 , 文章类型: 研究论文,,卷期:2008年76-1]
- Nickel octaethylporphyrin (NiOEP)-dihexylbithiophene (DHBTh) derivs. combined with pyridine (Pyr) and pyrimidine (Pym) as proton-acceptable rings (PAR) were synthesized, describable as NiOEP-DHBTh-PAR, in which all the N...
- Reversible encapsulation of terminal alkenes and alkynes.
[作者:Ajami, Dariush;Rebek, Julius, Jr.;,期刊:Heterocycles, 页码:169-176 , 文章类型: 研究论文,,卷期:2008年76-1]
- Equilibriums, Chemical Equilibriums, and Solutions) Section Mol. encapsulation is a modern form of recognition in which a host completely surrounds a guest mol. Unlike earlier covalent systems, reversible assembly allow...
- A simple chiral template for the synthesis of functionalized a-arylglycine derivatives.
[作者:Nakata, Hiyoku;Imai, Takahiro;Yokoshima, Satoshi;Fukuyama, Tohru;,期刊:Heterocycles, 页码:747-757 , 文章类型: 研究论文,,卷期:2008年76-1]
- A simple chiral template for the synthesis of arylglycine derivs. was developed. The chiral template, which is derived from valinol in 3 steps, reacts with electron-rich arom. compds. to afford adducts in good yield wit...
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