- Why a Proximity-Induced Diels-Alder Reaction Is So Fast
[作者:KRENSKE ELIZABETH H; PERRY EMMA W; JEROME STEVEN V; MAIMONE THOMAS J; BARAN PHIL S; HOUK K N,期刊:Organic Letters, 页码:3016-3019 , 文章类型: Article,,卷期:2012年14-12]
- Unlike normal Diels-Alder reactions of acyclic alkadienes with alkenes, the vinylbicyclo[2.2.2]octene employed in the Baran total synthesis of vinigrol undergoes a quantitative Diels-Alder reaction with a tethered alkene...
- HPLC-Assisted Automated Oligosaccharide Synthesis
[作者:GANESH N VIJAYA; FUJIKAWA KOHKI; TAN YIH HORNG; STINE KEITH J; DEMCHENKO ALEXEI V,期刊:Organic Letters, 页码:3036-3039 , 文章类型: Article,,卷期:2012年14-12]
- A standard HPLC was adapted to polymer supported oligosaccharide synthesis. Solution-based reagents are delivered using a software-controlled solvent delivery system. The reaction progress and completion can be monitored...
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