- A Sulfone-Based Strategy for the Preparation of 2,4-Disubstituted Furan Derivatives
[作者:HAINES NATHAN R; VANZANTEN AARON N; CUNEO ANTHONY A; MILLER JOHN R; ANDREWS WILLIAM J; CARLSON DAVID A; HARRINGTON RYAN M; KIEFER ADAM M; MASON JEREMY D; PIGZA JULIE A; MURPHREE S SHAUN,期刊:Journal of Organic Chemistry, 页码:8131-8137 , 文章类型: Article,,卷期:2011年76-19]
- 2,4-Disubstituted furans are prepared by treating 2,3-dibromo-l-phenylsulfonyl-l-propene (DBP, 2) with 1,3-diketones under basic conditions. The furan-forming step involves a deacetylation, and the selectivity of this pr...
- Total Synthesis of Dermostatin A
[作者:ZHANG YINGCHAO; ARPIN CAROLYNN C; CULLEN AARON J; MITTONFRY MARK J; SAMMAKIA TAREK,期刊:Journal of Organic Chemistry, 页码:7641-7653 , 文章类型: Article,,卷期:2011年76-19]
- The concise total synthesis of dermostatin A is described. Highlights include a two-directional application of the asymmetric acetate aldol method developed in our lab, a novel diastereotopic-group-selective acetal isome...
- Alkoxy Radical Cyclizations onto Silyl Enol Ethers Relative to Alkene Cyclization, Hydrogen Atom Transfer, and Fragmentation Reactions
[作者:RUEDABECERRIL MONTSERRAT; LEUNG JOE C T; DUNBAR CHRISTINE R; SAMMIS GLENN M,期刊:Journal of Organic Chemistry, 页码:7720-7729 , 文章类型: Article,,卷期:2011年76-19]
- This study examines the chemoselectivity of alkoxy radical cyclizations onto silyl enol ethers compared to competing cyclizations, 1,5-hydrogen atom transfers (1,5-HATs), and beta-fragmentations. Cyclization onto silyl e...
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