- Dewetting on Curved Interfaces: A Simple Route to Polymer Nanostructures
[作者:Chen, D; Zhao, W; Wei, DG; Russell, TP,期刊:Macromolecules, 页码:8020-8027 , 文章类型: Article,,卷期:2011年44-20]
- The dewetting behavior of polystyrene (PS) films immersed in nonsolvent, ethylene glycol, was investigated at temperatures above the glass transition temperature on planar interfaces and on the walls of cylindrical nanop...
- Synthesis of Complex Multiblock Copolymers via a Simple Iterative Cu(0)-Mediated Radical Polymerization Approach
[作者:Boyer, C; Soeriyadi, AH; Zetterlund, PB; Whittaker, MR,期刊:Macromolecules, 页码:8028-8033 , 文章类型: Article,,卷期:2011年44-20]
- Controlled/living radical polymerization is an efficient technique for the synthesis of well-defined polymeric architectures, including copolymers, block copolymers, stars, graft, and variations thereof. In this article,...
- Cooperative Segmental Motions in Ethyl Acrylate/Triethylene Glycol Dimethacrylate Copolymer Networks Studied by Dielectric Techniques
[作者:Stathopoulos, AT; Kyritsis, A; Ferrer, GG; Ribelles, JLG; Christodoulides, C; Pissis, P,期刊:Macromolecules, 页码:8233-8244 , 文章类型: Article,,卷期:2011年44-20]
- The molecular dynamics of ethyl acrylate/triethylene glycol dimethacrylate (EA/TrEGDMA) copolymer networks on the overall composition range were investigated thoroughly by employing dielectric techniques: thermally stimu...
- Origin of Initial Uncontrolled Polymerization and Its Suppression in the Copper(0)-Mediated Living Radical Polymerization of Methyl Acrylate in a Nonpolar Solvent
[作者:West, AG; Hornby, B; Tom, J; Ladmiral, V; Harrisson, S; Perrier, S,期刊:Macromolecules, 页码:8034-8041 , 文章类型: Article,,卷期:2011年44-20]
- We report the controlled polymerization of methyl acrylate in the presence of elemental copper at room temperature in a nonpolar solvent. As in single electron transfer (SET) living radical polymerization with nonactivat...
- Influence of Zwitterions on Thermomechanical Properties and Morphology of Acrylic Copolymers: Implications for Electroactive Applications
[作者:Wu, TY; Beyer, FL; Brown, RH; Moore, RB; Long, TE,期刊:Macromolecules, 页码:8056-8063 , 文章类型: Article,,卷期:2011年44-20]
- n-Butyl acrylate-based zwitterionomers and ionomers containing 3-[[2-(methacryloyloxy)ethyn(dimethypammonio]-1-propanesulfonate (SBMA) and 2-[butyl(dimethyl)amino]ethyl methacrylate methanesulfonate (BDMAEMA MS), respect...
- Sorbitol-POSS Interactions on Development of Isotactic Polypropylene Composites
[作者:Roy, S; Scionti, V; Jana, SC; Wesdemiotis, C; Pischera, AM; Espe, MP,期刊:Macromolecules, 页码:8064-8079 , 文章类型: Article,,卷期:2011年44-20]
- This study investigates the nature of interactions between the molecules of polyhedral oligomeric silsesquioxane (POSS) containing silanol functionalities (silanol POSS) and di(benzylidene)sorbitol (DBS) encountered in t...
- In Situ Synchrotron X-ray Scattering Study on Isotactic Polypropylene Crystallization under the Coexistence of Shear Flow and Carbon Nanotubes
[作者:Chen, YH; Zhong, GJ; Lei, J; Li, ZM; Hsiao, BS,期刊:Macromolecules, 页码:8080-8092 , 文章类型: Article,,卷期:2011年44-20]
- The crystallization of isotactic polypropylene (iPP) under the coexistence of shear flow and carbon nanotubes (CNTs) was investigated by means of in situ synchrotron X-ray scattering techniques, i.e. wide-angle X-ray dif...
- Reduced Crystallinity and Mobility of Nylon-6 Confined near the Organic-Inorganic Interface in a Phosphate Glass-Rich Nanocomposite Detected by (1)H-(13)C NMR
[作者:Rawal, A; Kong, XQ; Meng, Y; Otaigbe, JU; Schmidt-Rohr, K,期刊:Macromolecules, 页码:8100-8105 , 文章类型: Article,,卷期:2011年44-20]
- The effects of confinement of solid polyamide 6 in a nanocomposite with a rigid inorganic glass, a hybrid organic inorganic material with potential applications in opto-electronics, gas/liquid barrier membranes, and hete...
- Linking Network Microstructure to Macroscopic Properties of Siloxane Elastomers Using Combined Nuclear Magnetic Resonance and Mesoscale Computational Modeling
[作者:Mayer, BP; Lewicki, JP; Weisgraber, TH; Small, W; Chinn, SC; Maxwell, RS,期刊:Macromolecules, 页码:8106-8115 , 文章类型: Article,,卷期:2011年44-20]
- It is well established that many fundamental properties of polymer materials are directly governed by chain dynamics, and both experimental and computational efforts to probe this motional spectrum have been manifold. Re...
- Mixed-Salt Effects on the Ionic Conductivity of Lithium-Doped PEO-Containing Block Copolymers
[作者:Young, WS; Albert, JNL; Schantz, AB; Epps, TH,期刊:Macromolecules, 页码:8116-8123 , 文章类型: Article,,卷期:2011年44-20]
- We demonstrate a simple, yet effective, mixed-salt method to increase the room temperature ionic conductivity of lithium-doped block copolymer electrolyte membranes by suppressing the crystalline phases in the conducting...
- Homogeneous Dynamics within Inhomogeneous Environment in Semicrystalline Polymers
[作者:Sanz, A; Nogales, A; Ezquerra, TA; Haussler, W; Soccio, M; Lotti, N; Munari, A,期刊:Macromolecules, 页码:8124-8128 , 文章类型: Article,,卷期:2011年44-20]
- We show that the combination of dielectric with neutron spin echo measurements performed in a model deuterated polymer as poly(ethylene terephthalate) suggests that the dynamics of semicrystalline polymers occurs in an h...
- Structure of Polymer Tethered Highly Grafted Nanoparticles
[作者:Goel, V; Pietrasik, J; Dong, HC; Sharma, J; Matyjaszewski, K; Krishnamoorti, R,期刊:Macromolecules, 页码:8129-8135 , 文章类型: Article,,卷期:2011年44-20]
- Spherical nanoparticles of silica grafted with a dense brush of low-polydispersity polymers prepared by living radical polymerization are shown to form ordered crystalline structures. The minimum distance between nanopar...
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