- Controlling Blend Film Morphology by Varying Alkyl Side Chain in Highly Coplanar Donor-Acceptor Copolymers for Photovoltaic Application
[作者:Li, YW; Chen, YJ; Liu, X; Wang, Z; Yang, XM; Tu, YF; Zhu, XL,期刊:Macromolecules, 页码:6370-6381 , 文章类型: Article,,卷期:2011年44-16]
- A series of varied length alkyl substituted donor acceptor (D A) conjugated copolymers with benzo [1,2-b:4,5-b']dithiophene (BDT) as donor and thiophene rings attached to both sides of the benzothiadiazole (TBT) moieties...
- Thionyl Chloride-Catalyzed Preparation of Microporous Organic Polymers through Aldol Condensation
[作者:Zhao, YC; Zhou, D; Chen, Q; Zhang, XJ; Bian, N; Qi, AD; Han, BH,期刊:Macromolecules, 页码:6382-6388 , 文章类型: Article,,卷期:2011年44-16]
- We demonstrated the synthesis of five kinds of microporous organic polymers based on aldol self-condensation of di- and multiacetyl-containing building blocks catalyzed by thionyl chloride. The alpha,beta-unsaturated ket...
- Poly(3-dodecylthienylenevinylene)s: Regioregularity and Crystallinity
[作者:Zhang, C; Sun, JY; Li, R; Sun, SS; Lafalce, E; Jiang, XM,期刊:Macromolecules, 页码:6389-6396 , 文章类型: Article,,卷期:2011年44-16]
- A series of poly(dodecylthienylenevinylenes), C-12-PTVs-a: b, with tunable regioregularity and solubility have been synthesized using two isomeric comonomers with molar ratios from 0:10 to 5:5, and characterized by NMR s...
- Synthesis of 1-Vinyl-3-ethylimidazolium-Based Ionic Liquid (Co)polymers by Cobalt-Mediated Radical Polymerization
[作者:Detrembleur, C; Debuigne, A; Hurtgen, M; Jerome, C; Pinaud, J; Fevre, M; Coupillaud, P; Vignolle, J; Taton, D,期刊:Macromolecules, 页码:6397-6404 , 文章类型: Article,,卷期:2011年44-16]
- The cobalt-mediated radical polymerization (CMRP) of 1-vinyl-3-ethylimidazolium bromide (VEtImBr) is described. Polymerizations were performed at 30 degrees C in solution either in dimethylformamide (DMF) or in methanol ...
- Highly Phosphonated Polypentafluorostyrene
[作者:Atanasov, V; Kerres, J,期刊:Macromolecules, 页码:6416-6423 , 文章类型: Article,,卷期:2011年44-16]
- The synthesis and conductivity of highly phosphonated polypentafluorostyrene are demonstrated. Efficient postphosphonation (90%) was achieved via the classical nucleophilic aromatic substitution (S-N(Ar)) Michaelis-Arbuz...
- Highly Ordered Nanoporous Thin Films from Photocleavable Block Copolymers
[作者:Zhao, H; Gu, WY; Sterner, E; Russell, TP; Coughlin, EB; Theato, P,期刊:Macromolecules, 页码:6433-6440 , 文章类型: Article,,卷期:2011年44-16]
- Poly(styrene-block-ethylene oxide) with an o-nitrobenzyl ester photocleavable junction (PS-hv-PEO) was synthesized by a combined RAFT polymerization and "click chemistry" approach and represents the first report utilizin...
- Crystal Structure Analysis of Poly(L-lactic Acid) alpha Form On the basis of the 2-Dimensional Wide-Angle Synchrotron X-ray and Neutron Diffraction Measurements
[作者:Wasanasuk, K; Tashiro, K; Hanesaka, M; Ohhara, T; Kurihara, K; Kuroki, R; Tamada, T; Ozeki, T; Kanamoto, T,期刊:Macromolecules, 页码:6441-6452 , 文章类型: Article,,卷期:2011年44-16]
- The crystal structure of poly(L-lactic acid) (PLLA) alpha form has been analyzed in detail by utilizing the 2-dimensional wide-angle X-ray (WAXD) and neutron diffraction (WAND) data measured for the ultradrawn sample. Th...
- Development of Intermolecular Structure and Beta-phase of Random Poly[9,9-bis(2-ethylhexyl)fluorene]-co-(9,9-dioctylfluorene) in Methylcyclohexane
[作者:Knaapila, M; Bright, DW; Nehls, BS; Garamus, VM; Almasy, L; Schweins, R; Scherf, U; Monkman, AP,期刊:Macromolecules, 页码:6453-6460 , 文章类型: Article,,卷期:2011年44-16]
- We present small-angle neutron scattering (SANS) and optical absorption studies of random poly[9,9-bis(2-ethylhexyl)fluorene]-co-(9,9-dioctylfluorene) (PF2/6-F8) mixed with deuterated methylcyclohexane (MCH-d(14)) at roo...
- Electrospinning Superhydrophobic Fibers Using Surface Segregating End-Functionalized Polymer Additives
[作者:Hardman, SJ; Muhamad-Sarih, N; Riggs, HJ; Thompson, RL; Rigby, J; Bergius, WNA; Hutchings, LR,期刊:Macromolecules, 页码:6461-6470 , 文章类型: Article,,卷期:2011年44-16]
- We describe here a facile route for the in situ modification of the surface properties of fibers produced by electrospinning polystyrene containing small quantities of compatible polymer additives, end-functionalized wit...
- Polymer of Intrinsic Microporosity Incorporating Thioamide Functionality: Preparation and Gas Transport Properties
[作者:Mason, CR; Maynard-Atem, L; Al-Harbi, NM; Budd, PM; Bernardo, P; Bazzarelli, F; Clarizia, G; Jansen, JC,期刊:Macromolecules, 页码:6471-6479 , 文章类型: Article,,卷期:2011年44-16]
- A novel polymer of intrinsic microporosity, thioamide-PIM-1, has been prepared by postmodification of PIM-1, using phosphorus pentasulfide as a thionating agent in the presence of sodium sulfite. The chemistry was first ...
- Microwave-Exfoliated Graphite Oxide/Polycarbonate Composites
[作者:Potts, JR; Murali, S; Zhu, YW; Zhao, X; Ruoff, RS,期刊:Macromolecules, 页码:6488-6495 , 文章类型: Article,,卷期:2011年44-16]
- We present the first report of polymer composites using microwave-exfoliated graphite oxide (MEGO) as filler, a high surface area carbon material that resembles graphene on a local scale. MEGO has a "wormlike" layered st...
- Crystallization Behavior of Carbon Nanotube-Polylactide Nanocomposites
[作者:Barrau, S; Vanmansart, C; Moreau, M; Addad, A; Stoclet, G; Lefebvre, JM; Seguela, R,期刊:Macromolecules, 页码:6496-6502 , 文章类型: Article,,卷期:2011年44-16]
- The crystallization kinetics and the resulting structure and morphology of polylactide (PLA) were investigated in the presence of carbon nanotubes (CNTs). Nanocomposite samples prepared by solution and melt mixing presen...
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