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  • Aromaticity and Relative Stabilities of Azines
    [作者:WANG YAN; WU JUDY ICHIA; LI QIANSHU; SCHLEYER PAUL VON RAGUE,期刊:Organic Letters, 页码:4824-4827 , 文章类型: Article,,卷期:2010年12-21]
  • The most refined nucleus-independent chemical shift index (NICS(0)(pi zz)) and the extra cyclic resonance energies (ECREs), based on the block localized wave function (BLW) method, show that the aromaticity of all azines...
  • Guest Recognition in a Partially Bridged Deep Cavitand
    [作者:BUSSERON ERIC; REBEK JULIUS JR,期刊:Organic Letters, 页码:4828-4831 , 文章类型: Article,,卷期:2010年12-21]
  • The synthesis of a new deep cavitand partially bridged via disulfide bonds is described. Its thermodynamic and kinetic complexation parameters are compared with those of an unbridged analogue. The disulfide bridges cause...
  • Unusual Molecular Conformations in Fluorinated, Contorted Hexabenzocoronenes
    [作者:LOO YUEHLIN; HISZPANSKI ANNA M; KIM BUMJUNG; WEI SUJUN; CHIU CHIENYANG; STEIGERWALD MICHAEL L; NUCKOLLS COLIN,期刊:Organic Letters, 页码:4840-4843 , 文章类型: Article,,卷期:2010年12-21]
  • Fluorinated, contorted hexabenzocoronenes (HBCs) have been synthesized in a facile manner via Suzuki-Miyaura coupling of fluorinated phenyl boronic acids followed by photocyclization and Scholl cyclization. In addition t...
  • Aromatization of Fulvene by Complexation with Lithium
    [作者:OZIMINSKI W P; KRYGOWSKI T M; FOWLER P W; SONCINI A,期刊:Organic Letters, 页码:4880-4883 , 文章类型: Article,,卷期:2010年12-21]
  • At the B3LYP/6-311++G(d,p) level, approach of a lithium atom to a face of the fulvene molecule leads to formation of a complex with binding energy 41 kcal/mol and significant ion-pair character. The fulvene moiety gains ...