- Humidity-Dependent DC Conductivity of Polyelectrolyte Multi layers: Protons or Other Small Ions as Charge Carriers?
[作者:Akgol, Y; Cramer, C; Hofmann, C; Karatas, Y; Wiemhofer, HD; Schonhoff, M,期刊:Macromolecules, 页码:7282-7287 , 文章类型: Article,,卷期:2010年43-17]
- A range of different combinations of polyelectrolytes is employed to form multilayers by layer-by-layer assembly, which are investigated by impedance spectroscopy. In particular, the alkali counterion employed in the lay...
- New Dual Initiators To Combine Quasiliving Carbocationic Polymerization and Atom Transfer Radical Polymerization
[作者:Zhu, YL; Storey, RF,期刊:Macromolecules, 页码:7048-7055 , 文章类型: Article,,卷期:2010年43-17]
- New dual initiators, 3,3,5-trimethyl-5-chlorohexyl 2-bromopropionate (IB2BP) and 3,3,5-trimethyl-5-chlorohexyl 2-bromo-2-methylpropionate (IB2BMP), which contain initiating sites for both carbocationic polymerization and...
- Interdiffusion in Polyelectrolyte Multi layers
[作者:Soltwedel, O; Ivanova, O; Nestler, P; Muller, M; Kohler, R; Helm, CA,期刊:Macromolecules, 页码:7288-7293 , 文章类型: Article,,卷期:2010年43-17]
- Using neutron reflectivity, the internal structure of polyelectrolyte multilayers is described on the nanoscale. Each film consists of a protonated and a deuterated block, built from x protonated and y deuterated polycat...
- Solution Behavior of Polystyrene-Polyisoprene Miktoarm Block Copolymers in a Selective Solvent for Polyisoprene
[作者:Hinestrosa, JP; Alonzo, J; Osa, M; Kilbey, SM,期刊:Macromolecules, 页码:7294-7304 , 文章类型: Article,,卷期:2010年43-17]
- The dynamics and self-assembly of polystyrene- (PS-) polyisoprene (PI) miktoarm (mixed-arm) block copolymers in n-hexane, a selective solvent for PI, are investigated. The miktoarms present a branched arrangement in the ...
- Formation and Thermally-Induced Disruption of Nanowhiskers in Poly(3-hexylthiophene)/Xylene Gel Studied by Small-Angle X-ray Scattering
[作者:Chen, CY; Chan, SH; Li, JY; Wu, KH; Chen, HL; Chen, JH; Huang, WY; Chen, SA,期刊:Macromolecules, 页码:7305-7311 , 文章类型: Article,,卷期:2010年43-17]
- We identified the formation of nanowhiskers of poly(3-hexylthiophene) (P3HT) in the gel with xylene in situ by means of small-angle X-ray scattering (SAXS). In the freshly prepared solution, the rodlike segments of P3HT ...
- Synthesis and Topological Conversion of an 8-shaped Poly(THF) Having a Metathesis-Cleavable Unit at the Focal Position
[作者:Ishikawa, K; Yamamoto, T; Harada, H; Tezuka, Y,期刊:Macromolecules, 页码:7062-7067 , 文章类型: Article,,卷期:2010年43-17]
- A pair of 8-shaped poly(tetrahydrofuran)s, poly(THF)s, having a metathesis-cleavable olefinic unit of isomeric forms at the focal position, IIa and IIb, has been synthesized through an electrostatic self-assembly and cov...
- PNIPAm-PEO-PPO-PEO-PNIPAm Pentablock Terpolymer: Synthesis and Chain Behavior in Aqueous Solution
[作者:Mei, AX; Guo, XL; Ding, YW; Zhang, XH; Xu, JT; Fan, ZQ; Du, BY,期刊:Macromolecules, 页码:7312-7320 , 文章类型: Article,,卷期:2010年43-17]
- The double thermosensitive and narrow dispersed PNIPAm110-PEO100-PPO65-PEO10-PNIPAm110 pentablock terpolymer was synthesized by the typical atomic transfer radical polymerization (ATRP) method with N-isopropylacrylamide ...
- Investigation of Polymerization Mechanisms of Poly(n-Butyl Acrylate)s Generated in Different Solvents by LC-ESI-MS2
[作者:Song, JK; van Velde, JW; Vertommen, LLT; van der Ven, LGJ; Heeren, RMA; van den Brink, OF,期刊:Macromolecules, 页码:7082-7089 , 文章类型: Article,,卷期:2010年43-17]
- Liquid chromatography-electrospray ionization-tandem mass spectrometry (LC-ESI-MS2) was employed for the characterization of three poly(n-butyl acrylate)s. These polymers were produced at high temperature using the same ...
- Thermorheological Behavior of Various Short- and Long-Chain Branched Polyethylenes and Their Correlations with the Molecular Structure
[作者:Kessner, U; Kaschta, J; Stadler, FJ; Le Duff, CS; Drooghaag, X; Munstedt, H,期刊:Macromolecules, 页码:7341-7350 , 文章类型: Article,,卷期:2010年43-17]
- This paper deals with the characterization of a broad range of linear polyethylenes (PE) by means of thermorheology. It is demonstrated, in which way the thermorheological behavior can be related to the comonomer type an...
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