- Nucleophile-Initiated Thiol-Michael Reactions: Effect of Organocatalyst, Thiol, and Ene
[作者:Chan, JW; Hoyle, CE; Lowe, AB; Bowman, M,期刊:Macromolecules, 页码:6381-6388 , 文章类型: Article,,卷期:2010年43-15]
- A detailed evaluation of the kinetics of the thiol-Michael reaction between hexanethiol and hexyl acrylate is described. It is shown that primary amines are more effective catalysts than either secondary or tertiary amin...
- High Performance Cross-Linked Poly(2-acrylamido-2-methylpropanesulfonic acid)-Based Proton Exchange Membranes for Fuel Cells
[作者:Diao, HB; Yan, F; Qiu, LH; Lu, JM; Lu, XH; Lin, BC; Li, Q; Shang, SM; Liu, WM; Liu, JG,期刊:Macromolecules, 页码:6398-6405 , 文章类型: Article,,卷期:2010年43-15]
- Poly(2-acrylamido-2-methylpropanesulfonic acid) (PAMPS) has been used for the preparation of proton exchange membranes (PEMs) due to the superior ability of sulfonic acid groups originated from AMPS in supporting proton ...
- Synthesis, Cocrystallization, and Microphase Separation of All-Conjugated Diblock Copoly(3-alkylthiophene)s
[作者:Ge, J; He, M; Qiu, F; Yang, YL,期刊:Macromolecules, 页码:6422-6428 , 文章类型: Article,,卷期:2010年43-15]
- A series of all-conjugated diblock copoly(3-alkylthiophene)s with varying alkyl chain length, poly(3-butylthiophene)-b-poly(3-hexylthiophcne) (P3BT-P3HT), poly(3-butylthiophene)-b-poly(3-dodecyl-thiophene) (P3BT-P3DDT), ...
- Binodal Compositions of Polyeleetrolyte Complexes
[作者:Spruijt, E; Westphal, AH; Borst, JW; Stuart, MAC; van der Gucht, J,期刊:Macromolecules, 页码:6476-6484 , 文章类型: Article,,卷期:2010年43-15]
- When oppositely charged polyelectrolytes arc mixed below a critical salt concentration, their mixtures show macroscopic phase separation into a dilute and a dense, polyclectrolyte complex phase. Binodal compositions of t...
- Biodegradable Core/Shell Fibers by Coaxial Electrospinning: Processing, Fiber Characterization, and Its Application in Sustained Drug Release
[作者:Wang, C; Yan, KW; Lin, YD; Hsieh, PCH,期刊:Macromolecules, 页码:6389-6397 , 文章类型: Article,,卷期:2010年43-15]
- Solutions of two biodegradable polymers, that is, poly(DL-lactic acid) (PDLLA) and poly(3-hydroxy butyrate) (PHB), were individually delivered to the inner and outer channel of a coaxial-tube spinneret for electrospinnin...
- Effect of Dilution on Structure and Properties of Polyurethane Networks. Pregel and Postgel Cyclization and Phase Separation
[作者:Duskova-Smrckova, M; Valentova, H; Durackova, A; Dusek, K,期刊:Macromolecules, 页码:6450-6462 , 文章类型: Article,,卷期:2010年43-15]
- Bi-, tri-, and tetrafunctional star-shaped polyol precursors were cross-linked with a star-shaped triisocyanate and the effect of the presence of diluent during network formation on the gel-point conversion, alpha(crit),...
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