A series of novel structurally well-defined oligothienylene-ethynylene-based dendritic macromolecules up to the 3rd generation (G3) were successfully synthesized by a combination of Pd-catalyzed Sonogashira-type cross-co...
To introduce crown ethers into the struts of metal-organic frameworks (MOFs), general approaches have been developed for the syntheses of dicarboxylic acid dibenzo[30]crown-10 (DB30C10DA), dicarboxylic acid di-2,3-naphth...
The origin of the stability of a frustrated Lewis pair (FLP) tBu(3)P:B-(C6F5)(3) is investigated computationally to demonstrate the importance of the dispersion interaction. To this end, the interaction between alkyl-sub...