- Novel Biodegradable Poly(ester-ether)s: Copolymers from 1,4-Dioxan-2-one and D,L-3-Methyl-1,4-dioxan-2-one
[作者:Lochee, Y; Bhaw-Luximon, A; Jhurry, D; Kalangos, A,期刊:Macromolecules, 页码:7285-7291 , 文章类型: Article,,卷期:2009年42-19]
- Synthesis of random copolymers by the nonsequential polymerization of 1,4-dioxan-2-one With D,L,-3-methyl-1,4-dioxan-2-one was first investigated using a range of classical initiators. Experimental conditions such as tem...
- Multiblock Copolymers of Lactic Acid and Ethylene Glycol Containing Periodic Side-Chain Carboxyl Groups: Synthesis, Characterization, and Nanoparticle Preparation
[作者:Ankola, DD; Kumar, MNVR; Chiellini, F; Solaro, R,期刊:Macromolecules, 页码:7388-7395 , 文章类型: Article,,卷期:2009年42-19]
- Multiblock copolymers containing periodically spaced side-chain carboxyl groups were obtained by a two-step synthesis involving the preparation of ABA triblock prepolymers of lactic acid (A block) and ethylene glycol (B ...
- Relation between Photoactive Layer Thickness, 3D Morphology, and Device Performance in P3HT/PCBM Bulk-Heterojunction Solar Cells
[作者:van Bavel, S; Sourty, E; de With, G; Frolic, K; Loos, J,期刊:Macromolecules, 页码:7396-7403 , 文章类型: Article,,卷期:2009年42-19]
- To get an efficient organic solar cell, as much light as possible should be absorbed by the photoactive layer; as a consequence, thick layers should be preferable. However, it is often observed that much thinner photoact...
- Synthesis of Dendritic Polystyrenes from an Anionic Inimer
[作者:Sun, W; He, JP; Wang, XJ; Zhang, C; Zhang, HD; Yang, YL,期刊:Macromolecules, 页码:7309-7317 , 文章类型: Article,,卷期:2009年42-19]
- An anionic inimer (a monomer with an initiating site) is prepared by monoaddition of sec-butyllithium and 1,3-bis(1-phenylethenyl)benzene (MDDPE) in tetrahydrofuran (THF) at low temperature. The selectivity of monoadditi...
- Mechanistic Studies of Photoinitiated Free Radical Polymerization Using a Bifunctional Thioxanthone Acetic Acid Derivative as Photoinitiator
[作者:Karasu, F; Arsu, N; Jockusch, S; Turro, NJ,期刊:Macromolecules, 页码:7318-7323 , 文章类型: Article,,卷期:2009年42-19]
- A bifunctional photoinitiator for free radical polymerization, thioxanthone catechol-O,O'-diacetic acid, was synthesized, characterized, and compared to photoinitiator parameters of the monofunctional analogue, 2-(carbox...
- Single-Electron Transfer Living Radical Polymerization (SET-LRP) of Methyl Methacrylate (MMA) with a Typical RAFT Agent as an Initiator
[作者:Zhang, ZB; Wang, WX; Xia, HD; Zhu, J; Zhang, W; Zhu, XL,期刊:Macromolecules, 页码:7360-7366 , 文章类型: Article,,卷期:2009年42-19]
- A typical reversible addition-fragmentation chain transfer (RAFT) agent, 2-cyanoprop-2-yl 1-dithionaphthalate (CPDN), was used as a single electron transfer-living radical polymerization (SET-LRP) initiator for methyl me...
- Local Water Dynamics in Coacervated Polyelectrolytes Monitored through Dynamic Nuclear Polarization-Enhanced H-1 NMR
[作者:Kausik, R; Srivastava, A; Korevaar, PA; Stucky, G; Waite, JH; Han, S,期刊:Macromolecules, 页码:7404-7412 , 文章类型: Article,,卷期:2009年42-19]
- We present the first study of quantifying the diffusion coefficient of interfacial water oil polyelectrolyte surfaces of systems fully dispersed in bulk water under ambient conditions. Such measurements were made possibl...
- Hydrodynamic Analysis of Well-Defined Flexible Linear Macromolecules of Low Molar Mass
[作者:Pavlov, GM; Amoros, D; Ott, C; Zaitseva, II; de la Torre, JG; Schubert, US,期刊:Macromolecules, 页码:7447-7455 , 文章类型: Article,,卷期:2009年42-19]
- Samples of poly(styrene-diphenylethylene) copolymers of narrow molar mass distribution were studied by molecular hydrodynamic methods. The values of velocity sedimentation coefficient, frictional ratio, translational dif...
- Onset of Entanglements Revisited. Topological Analysis
[作者:Tzoumanekas, C; Lahmar, F; Rousseau, B; Theodorou, DN,期刊:Macromolecules, 页码:7474-7484 , 文章类型: Article,,卷期:2009年42-19]
- In a series of two papers, west tidy the onset of entanglements and the transition from Rouse-type to reptation dynamics, in the context of dissipative particle dynamics (DPD) simulations of a coarse-grained polymer melt...
- Salt Effects on Complexes of Oppositely Charged Macromolecules Having Different Affinity to Water
[作者:Krotova, MK; Vasilevskaya, VV; Leclercq, L; Boustta, M; Vert, M; Khokhlov, AR,期刊:Macromolecules, 页码:7495-7503 , 文章类型: Article,,卷期:2009年42-19]
- The influence of salt concentration on the size and on the thermodynamic stability of interpolymer complexes composed of oppositely charged macroions having different affinity to solvent was studied from a theoretical vi...
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