- Unprecedented steric deformation of ortho-carborane.
[作者:Hutton, Brian W.;MacIntosh, Fraser;Ellis, David;Herisse, Fabien;Macgregor, Stuart A.;McKay, David;Petrie-Armstrong, Victoria;Rosair, Georgina M.;Perekalin, Dmitry S.;Tricas, Hugo;Welch, Alan J.;,期刊:Chemical Communications, 页码:5345-5347 , 文章类型: 研究论文,,卷期:2008年-42]
- The redn. and subsequent oxidn. of meta-carboranes contg. bulky groups attached to the cage C atoms affords sterically-crowded ortho-carboranes with unprecedentedly long C-C connectivities. All the compds. prepd. were s...
- Asymmetric 1,3-dipolar cycloaddition with a P-stereogenic dipolarophile: An efficient approach to novel P-stereogenic 1,2-diphosphine systems.
[作者:Vinokurov, Nikolai;Pietrusiewicz, K. Michal;Frynas, Slawomir;Wiebcke, Michael;Butenschoen, Holger;,期刊:Chemical Communications, 页码:5408-5410 , 文章类型: 研究论文,,卷期:2008年-42]
- The asym. 1,3-dipolar cycloaddn. of a P-stereogenic dipolarophile to C,N-diphenylnitrone led to previously unknown P-stereogenic isoxazolinyl diphosphine dioxides in enantio- and diastereomerically pure form. Their ster...
- Internal amide-triggered cycloaromatization of maduropeptin-like nine-membered enediyne.
[作者:Norizuki, Yutaro;Komano, Kazuo;Sato, Itaru;Hirama, Masahiro;,期刊:Chemical Communications, 页码:5372-5374 , 文章类型: 研究论文,,卷期:2008年-42]
- Bicyclododecenediynylidenemethyl benzenepropanamide I and its (Z)-alkylidene stereoisomer, both contg. the core ring system of maduropeptin without the sugar and macrolactam moieties, are prepd. Mesylation of I yields bi...
- Non-hydrolytic synthesis of mesoporous silica-titania catalysts for the mild oxidation of sulfur compounds with hydrogen peroxide.
[作者:Cojocariu, Ana Mihaela;Mutin, P. Hubert;Dumitriu, Emil;Fajula, Francois;Vioux, Andre;Hulea, Vasile;,期刊:Chemical Communications, 页码:5357-5359 , 文章类型: 研究论文,,卷期:2008年-42]
- A SiO2-TiO2 mesoporous xerogel prepd. in one step by a non-hydrolytic route shows excellent performance in the mild oxidn. of sulfides, sulfoxides and thiophenes with aq. solns. of H2O2.
- A stable enol in small ring systems: clear differentiation between penta- and tri-valency of phosphorus atoms.
[作者:Ionkin, Alex S.;Marshall, William J.;Fish, Brian M.;Schiffhauer, Matthew F.;McEwen, Charles N.;,期刊:Chemical Communications, 页码:5432-5434 , 文章类型: 研究论文,,卷期:2008年-42]
- The first stable enols in 1,2-dihydrophosphetes were synthesized and structurally characterized with intermol. hydrogen bonds to phosphoryl groups in 10-membered dimeric structures; in contrast, a trivalent analog exists...
- Structural complexity of the magnesiation of furan: an octadecanuclear product with a subporphyrin-like Mg3(2,5-fur-di-yl)3 substructure.
[作者:Blair, Victoria L.;Kennedy, Alan R.;Klett, Jan;Mulvey, Robert E.;,期刊:Chemical Communications, 页码:5426-5428 , 文章类型: 研究论文,,卷期:2008年-42]
- Subjecting furan to sodium-mediated magnesiation via the new heteroleptic alkyl-amido reagent [(TMEDA)譔a(CH2SiMe3)(TMP)Mg(TMP)] produces the remarkable dodecasodium-hexamagnesium mol. [{(TMEDA)3Na6Mg3(CH2SiMe3)(2,5-C4H2O...
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