- Application of a Domino Friedel-Crafts Acylation/Alkylation Reaction to the Formal Syntheses of (?-Taiwaniaquinol B and (?-Dichroanone.
[作者:Tang, Shouchu;Xu, Yanfen;He, Jinmei;He, Yongping;Zheng, Jiyue;Pan, Xinfu;She, Xuegong;,期刊:Organic Letters, 页码:1855-1858 , 文章类型: 研究论文,,卷期:2008年10-9]
- An efficient acid-promoted domino Friedel-Crafts (FC) acylation/alkylation reaction has been developed for the construction of the core 6,5,6-ABC tricyclic skeleton (e.g. I) of taiwaniaquinoids. The formal total synthes...
- Efficient and Divergent Synthesis of Fully Substituted 1H-Pyrazoles and Isoxazoles from Cyclopropyl Oximes.
[作者:Wang, Kewei;Xiang, Dexuan;Liu, Jinying;Pan, Wei;Dong, Dewen;,期刊:Organic Letters, 页码:1691-1694 , 文章类型: 研究论文,,卷期:2008年10-9]
- Efficient and divergent one-pot synthesis of fully substituted 1H-pyrazoles and isoxazoles from cyclopropyl oximes based on reaction conditions selection is reported. Under Vilsmeier conditions (POCl3/DMF), substituted ...
- Synthesis of Homochiral Dihydroxy-4-nitroisoxazolines via One-Pot Asymmetric Dihydroxylation-Reduction.
[作者:Adamo, Mauro F. A.;Nagabelli, Murali;,期刊:Organic Letters, 页码:1807-1810 , 文章类型: 研究论文,,卷期:2008年10-9]
- A one-pot procedure to prep. a family of homochiral dihydroxy-4-nitroisoxazolines, e.g., I, is disclosed. This new methodol. affords the title compds. in good yields, excellent enantiopurity, and without the use of chro...
- Ir-Catalyzed Regio- and Enantioselective Friedel-Crafts-Type Allylic Alkylation of Indoles.
[作者:Liu, Wen-Bo;He, Hu;Dai, Li-Xin;You, Shu-Li;,期刊:Organic Letters, 页码:1815-1818 , 文章类型: 研究论文,,卷期:2008年10-9]
- Highly regio- and enantioselective Ir-catalyzed Friedel-Crafts type allylic alkylation of indoles have been realized using [Ir(COD)Cl]2/phosphoramidite ligand, affording the branched products, e.g., I, with up to >97/3 b...
- Diastereoselective Brook Rearrangement-Mediated [3 + 4] Annulation: Application to a Formal Synthesis of (+)-Laurallene.
[作者:Sasaki, Michiko;Hashimoto, Azusa;Tanaka, Koudai;Kawahata, Masatoshi;Yamaguchi, Kentaro;Takeda, Kei;,期刊:Organic Letters, 页码:1803-1806 , 文章类型: 研究论文,,卷期:2008年10-9]
- The formal synthesis of (+)-laurallene, a halogenated eight-membered ring ether, was accomplished. The synthesis involves construction of a trans a,a'-disubstituted oxocene structure through a Brook rearrangement-mediat...
- Efficient Intermolecular Iron-Catalyzed Amidation of C-H Bonds in the Presence of N-Bromosuccinimide.
[作者:Wang, Zhe;Zhang, Yongming;Fu, Hua;Jiang, Yuyang;Zhao, Yufen;,期刊:Organic Letters, 页码:1863-1866 , 文章类型: 研究论文,,卷期:2008年10-9]
- system was developed that efficiently promotes amidation of benzylic sp3 C-H bonds in Et acetate under mild conditions. Thus, reaction of Ph2CH2 with PhCONH2 in EtOAc contg. FeCl2 and N-bromosuccinimide at 50?for six ho...
- Hexafluoroisopropanol as a Unique Solvent for Stereoselective Iododesilylation of Vinylsilanes.
[作者:Ilardi, Elizabeth A.;Stivala, Craig E.;Zakarian, Armen;,期刊:Organic Letters, 页码:1727-1730 , 文章类型: 研究论文,,卷期:2008年10-9]
- Stereoselective prepn. of iodoalkenes from vinylsilanes is described. 1,1,1,3,3,3-Hexafluoroisopropanol serves as a unique solvent that ensures high yields and stereoselectivities in the iododesilylation of a variety of ...
- Expedient Synthesis of the Tetracyclic Core of ent-Nakadomarin A.
[作者:Deng, Haibing;Yang, Xiaobao;Tong, Zhaolong;Li, Zhong;Zhai, Hongbin;,期刊:Organic Letters, 页码:1791-1793 , 文章类型: 研究论文,,卷期:2008年10-9]
- An efficient eight-step assembly of the tetracyclic core (ABCD rings), I, of ent-(+)-nakadomarin A, a bioactive hexacyclic marine alkaloid, has been realized with Sonogashira coupling, platinum(II)-promoted cascade cycli...
- Fluorescent Amino- and Thiopyronin Dyes.
[作者:Wu, Liangxing;Burgess, Kevin;,期刊:Organic Letters, 页码:1779-1782 , 文章类型: 研究论文,,卷期:2008年10-9]
- Highly fluorescent rhodamine/rosamine analogs (I) (Nu = NR2, NHR, or SCH2Ph; X = H or CO2Me) were prepd. from ketone (II). A direct route to novel heteroatom analogs of rhodamine and rosamine systems is described here. ...
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