- Total Synthesis of Wasabidienones B1 and B via SIBX-Mediated Hydroxylative Phenol Dearomatization.
[作者:Pouysegu, Laurent;Marguerit, Melanie;Gagnepain, Julien;Lyvinec, Gildas;Eatherton, Andrew J.;Quideau, Stephane;,期刊:Organic Letters, 页码:5211-5214 , 文章类型: 研究论文,,卷期:2008年10-22]
- The first total synthesis of the natural nondimerizing o-quinol (+)-wasabidienone B1 (I) was achieved from com. available 1,3,5-trimethoxybenzene. The key dearomatizing transformation was efficiently accomplished via a ...
- Carbonylative Cross-Coupling of ortho-Disubstituted Aryl Iodides.
[作者:Convenient Synthesis of Sterically Hindered Aryl Ketones. O'Keefe, B. Michael;Simmons, Nicholas;Martin, Stephen F.;,期刊:Organic Letters, 页码:5301-5304 , 文章类型: 研究论文,,卷期:2008年10-22]
- A mild and general protocol for the carbonylative cross-coupling of sterically hindered ortho-disubstituted aryl iodides is reported. Carbonylative Suzuki-Miyaura couplings of a variety of aryl boronic acids provide an a...
- Regiocontrolled Addition of Arylboronic Acids to Allenes Using Palladium and Platinum Catalysts.
[作者:Yoshida, Masahiro;Matsuda, Kennosuke;Shoji, Yasunobu;Gotou, Takahiro;Ihara, Masataka;Shishido, Kozo;,期刊:Organic Letters, 页码:5183-5186 , 文章类型: 研究论文,,卷期:2008年10-22]
- Studies about the regiocontrolled addn. of arylboronic acids to allenes using a palladium or a platinum catalyst have been described. The selectivity of the reaction can be altered by the choice of the metal reagent and...
- Photolabile Protection of 1,2- and 1,3-Diols with Salicylaldehyde Derivatives.
[作者:Kostikov, Alexey P.;Popik, Vladimir V.;,期刊:Organic Letters, 页码:5277-5280 , 文章类型: 研究论文,,卷期:2008年10-22]
- 1,2- And 1,3-diols, including carbohydrates, can be readily caged as acetals of 5-methoxy- or 5-hydroxysalicylaldehydes. Irradn. of these acetals with 300 nm light results in their efficient (F = 0.2-0.3) cleavage, rege...
- Relative and absolute stereochemistry of quinadoline B, an inhibitor of lipid droplet synthesis in macrophages.
[作者:Koyama, Nobuhiro;Inoue, Yusuke;Sekine, Masae;Hayakawa, Yoichi;Homma, Hiroshi;Oinmura, Satoshi;Tomoda, Hiroshi;,期刊:Organic Letters, 页码:5273-5276 , 文章类型: 研究论文,,卷期:2008年10-22]
- New fungal metabolites, designated quinadolines A (I) and B (II), were isolated from culture broth of Aspergillus sp. FKI-1746, and their structures were elucidated by NMR spectroscopy. The complete relative and abs. st...
- Cell-Permeable Esters of Diazeniumdiolate-Based Nitric Oxide Prodrugs.
[作者:Chakrapani, Harinath;Maciag, Anna E.;Citro, Michael L.;Keefer, Larry K.;Saavedra, Joseph E.;,期刊:Organic Letters, 页码:5155-5158 , 文章类型: 研究论文,,卷期:2008年10-22]
- Although O2-(2,4-dinitrophenyl) derivs. of diazeniumdiolate-based nitric oxide (NO) prodrugs bearing a free carboxylic acid group were activated by glutathione to release NO, these compds. were poor sources of intracellu...
- Chemiluminescence Change of Polyphenol Dendrimers with Different Core Molecules.
[作者:Agawa, Hiroki;Nakazono, Manabu;Nanbu, Shinkoh;Zaitsu, Kiyoshi;,期刊:Organic Letters, 页码:5171-5174 , 文章类型: 研究论文,,卷期:2008年10-22]
- Second generation polyphenol dendrimers (PDs) with different core mols. were synthesized, and their chemiluminescence (CL) was measured by oxidn. of PDs with H2O2 under alk. conditions. All of the PDs showed strong CL, ...
- Nucleophilic Addition of Potassium Alkynyltrifluoroborates to D-Glucal Mediated by BF3譕Et2: Highly Stereoselective Synthesis of a-C-glycosides.
[作者:Vieira, Adriano S.;Fiorante, Pedro F.;Hough, Thomas L. S.;Ferreira, Fernando P.;Ludtke, Diogo S.;Stefani, Helio A.;,期刊:Organic Letters, 页码:5215-5218 , 文章类型: 研究论文,,卷期:2008年10-22]
- A convenient, mild and highly stereoselective method for C-glycosidation (alkynylation) of D-glucal with various potassium alkynyltrifluoroborates, mediated by BF3譕Et2 and involving oxonium intermediates, preferentially ...
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