- Synthesis and Reactivity of a Novel Class of Long-Lived Ammonium Ylides: Derivatives of Benzo[b]pyrrolo[2,1-f][1.6]naphthyridine.
[作者:Voskressensky, Leonid G.;Vorobiev, Ilya V.;Borisova, Tatyana N.;Varlamov, Alexey V.;,期刊:Journal of Organic Chemistry, 页码:4596-4601 , 文章类型: 研究论文,,卷期:2008年73-12]
- Reaction of 10-cyanotetrahydrobenzo[b][1,6]naphthyridines I(R = H, Br, F, R1 = Me; R = H, F, NO2, R1 = iso-Pr) with activated alkynes affords stable benzo[b]pyrrolo[2,1-f][1,6]naphthyridin-4-ium ylides, e.g. II (R = H, B...
- Crystal Engineering for p-p Stacking via Interaction between Electron-Rich and Electron-Deficient Heteroaromatics.
[作者:Chang, Yu-Chang;Chen, Yu-Da;Chen, Chih-Hsin;Wen, Yuh-Sheng;Lin, Jiann T.;Chen, Hsing-Yin;Kuo, Ming-Yu;Chao, Ito;,期刊:Journal of Organic Chemistry, 页码:4608-4614 , 文章类型: 研究论文,,卷期:2008年73-12]
- New dipolar compds. contg. alternating electron-rich thieno[3,2-b]thiophene units and electron deficient units have been synthesized. Compds. with 5-pyrimidinyl (I) or benzothiazole (II) as the electron-deficient unit w...
- Photoaddition Reactions of 1,2-Diketones with Silyl Ketene Acetals.
[作者:Formation of b-Hydroxy-g-ketoesters. Cho, Dae Won;Lee, Hyang-Yeol;Oh, Sun Wha;Choi, Jung Hei;Park, Hea Jung;Mariano, Patrick S.;Yoon, Ung Chan;,期刊:Journal of Organic Chemistry, 页码:4539-4547 , 文章类型: 研究论文,,卷期:2008年73-12]
- Photochem. reactions taking place between 1,2-diketones and silyl ketene acetals and their excited state reaction mechanisms have been explored. Irradn. of benzene, acetone, or acetonitrile solns. contg. 1,2-diketones a...
- Nanoscale molecular rods with a new building block for solubility enhancement.
[作者:Wessig, Pablo;Moellnitz, Kristian;,期刊:Journal of Organic Chemistry, 页码:4452-4457 , 文章类型: 研究论文,,卷期:2008年73-12]
- A new building block bearing a [1,3]dioxolo[4,5-f][1,3]benzodioxole core was developed to enhance the soly. of mol. rods by lateral alkyl chains. On incorporation in mol. rods with oligospiroketal structure, the straigh...
- Substituent Effects on Aryltrifluoroborate Solvolysis in Water: Implications for Suzuki-Miyaura Coupling and the Design of Stable 18F-Labeled Aryltrifluoroborates for Use in PET Imaging.
[作者:Ting, Richard;Harwig, Curtis W.;Lo, Justin;Li, Ying;Adam, Michael J.;Ruth, Thomas J.;Perrin, David M.;,期刊:Journal of Organic Chemistry, 页码:4662-4670 , 文章类型: 研究论文,,卷期:2008年73-12]
- Whereas electron withdrawing substituents retard the rate of aryltrifluoroborate solvolysis, electron-donating groups enhance it. Herein is presented a Hammett anal. of the solvolytic lability of aryltrifluoroborates whe...
- A Novel Approach to the Synthesis of 6-Substituted Uracils in Three-Step, One-Pot Reactions.
[作者:Bardagi, Javier I.;Rossi, Roberto A.;,期刊:Journal of Organic Chemistry, 页码:4491-4495 , 文章类型: 研究论文,,卷期:2008年73-12]
- From the com. 6-chloro-2,4-dimethoxypyrimidine and by a photostimulated reaction with Me3Sn- ions, 2,4-dimethoxy-6-(trimethylstannyl)pyrimidine (I) was obtained in 95% yield. By the cross-coupling reaction of I with 1-i...
- Reaction of N-Methyl-5-tributylstannyl-4-fluoro-1H-pyrazole and Its Application to N-Methyl-chromeno[2,3-d]pyrazol-9-one Synthesis.
[作者:Hanamoto, Takeshi;Hashimoto, Eri;Miura, Masayuki;Furuno, Hiroshi;Inanaga, Junji;,期刊:Journal of Organic Chemistry, 页码:4736-4739 , 文章类型: 研究论文,,卷期:2008年73-12]
- N-Methylation by sequential treatment of 5-tributylstannyl-4-fluoro-1H-pyrazole with LDA and iodomethane regioselectively afforded the compd. N-methyl-5-tributylstannyl-4-fluoro-1H-pyrazole (I) in high yield. The addn. ...
- A domino annulation reaction under Willgerodt-Kindler conditions.
[作者:Kadzimirsz, Daniel;Kramer, Daniel;Sripanom, Lertnarong;Oppel, Iris M.;Rodziewicz, Pawel;Doltsinis, Nikos L.;Dyker, Gerald;,期刊:Journal of Organic Chemistry, 页码:4644-4649 , 文章类型: 研究论文,,卷期:2008年73-12]
- (Heterocyclic Compounds (More Than One Hetero Atom)) Section Butanone side chains at arenes and hetarenes, efficiently introduced by a Heck-type reaction, are transformed to annulated thieno[3,2-b]thiophenes, e.g. I, in ...
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