Organoboron compounds are useful in asymmetric synthesis. We have developed an efficient methodology for the highly enantioselective synthesis of tertiary boronic esters from the corresponding secondary benzylic alcohols...
A spherosilicate dendrimer (DMS-1) with closely spaced reaction sites (Si-H groups) on the dendrimer surface has been synthesized by stepwise silylation of double-four-ring silicate with chlorotriethoxysilane (ClSi(OEt)(...
Molecular ions in the form of pseudo-atoms are common structural motifs in chemistry, with properties that are transferrable between different compounds. We have determined one such property-the electronegativity-for the...
The complexation reactions between strontium (Sr(2+)) and octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO) were studied at the aqueous vertical bar 1,2-dichloroethane (w vertical bar DCE) and aqueous ver...
A series of new mononuclear and carboranylcarboxylate-bridged dinuclear copper(II) compounds containing the 1-CH(3)-2-CO(2)H-1,2-closo-C(2)B(10)H(10) carborane ligand (LH) has been synthesized. Reaction of different copp...