- Melt-Phase Synthesis and Properties of Triptycene-Containing Copolyesters
[作者:Liu, YC; Turner, SR; Wilkes, G,期刊:Macromolecules, 页码:4049-4056 , 文章类型: Article,,卷期:2011年44-11]
- A new triptycene diol (TD), triptycene-1,4-hydroquinonebis(2-hydroxyethyl) ether, was synthesized and was used to prepare a series of copolyesters with dimethyl 1,4-cyclohexanedicarboxylate (1,4-DMCD) by melt polycondens...
- Poly(2-cyclopropyl-2-oxazoline): From Rate Acceleration by Cyclopropyl to Thermoresponsive Properties
[作者:Bloksma, MM; Weber, C; Perevyazko, IY; Kuse, A; Baumgartel, A; Vollrath, A; Hoogenboom, R; Schubert, US,期刊:Macromolecules, 页码:4057-4064 , 文章类型: Article,,卷期:2011年44-11]
- The synthesis and microwave-assisted living cationic ring-opening polymerization of 2-cyclopropyl-2-oxazoline is reported revealing the fastest polymerization for an aliphatic substituted 2-oxazoline to date, which is as...
- Controlled Radical Polymerization of Vinyl Acetate Mediated by a Bis(imino)pyridine Vanadium Complex
[作者:Allan, LEN; Cross, ED; Francis-Pranger, TW; Hanhan, ME; Jones, MR; Pearson, JK; Perry, MR; Storr, T; Shaver, MP,期刊:Macromolecules, 页码:4072-4081 , 文章类型: Article,,卷期:2011年44-11]
- The mechanism of controlled radical polymerization of vinyl acetate using vanadium catalysts is investigated using a range of experimental and computational studies. Optimal control is achieved using the noninnocent bis-...
- Construction of Polypseudorotaxane from Low-Molecular Weight Monomers via Dual Noncovalent Interactions
[作者:Zhu, LL; Lu, MQ; Zhang, QW; Qu, DH; Tian, H,期刊:Macromolecules, 页码:4092-4097 , 文章类型: Article,,卷期:2011年44-11]
- The design and construction of polypseudorotaxanes via noncovalent interactions from low-molecular weight monomers (LMWMs) is playing an important role in the field of supramolecular polymers. In this work, we synthesize...
- Pseudo-Halide and Nitrate Derivatives of Grubbs and Grubbs-Hoveyda Initiators: Some Structural Features Related to the Alternating Ring-Opening Metathesis Copolymerization of Norborn-2-ene with Cyclic Olefins
[作者:Buchmeiser, MR; Ahmad, I; Gurram, V; Kumar, PS,期刊:Macromolecules, 页码:4098-4106 , 文章类型: Article,,卷期:2011年44-11]
- A series of novel Ru-alkylidene-based initiators, in which both chloride ligands were replaced by pseudo-halides or by nitrate, i.e., [Ru(NCO)(2)(IMesH(2))(C5H5N)(CHC6H5)] (1b), [Ru(CF3SO3)(2)(IMesH(2))(C5H5N)(CHC6H5)] (...
- Phenylethynyl and Phenol End-Capping Studies of Polybiphenyloxydiphenylsilanes for Cross-Linking and Enhanced Thermal Stability
[作者:Drake, K; Mukherjee, I; Mirza, K; Ji, HF; Wei, Y,期刊:Macromolecules, 页码:4107-4115 , 文章类型: Article,,卷期:2011年44-11]
- Polyaryloxydiphenylsilanes have been studied for decades and are known to be stable at high temperatures. Polybiphenyloxydiphenylsilane was synthesized to further study its high-temperature characteristics. However, cond...
- Arm-First Synthesis of Core-Cross-Linked Multiarm Star Polyethylenes by Coupling Palladium-Catalyzed Ethylene "Living" Polymerization with Atom-Transfer Radical Polymerization
[作者:Liu, PW; Landry, E; Ye, ZB; Joly, H; Wang, WJ; Li, BG,期刊:Macromolecules, 页码:4125-4139 , 文章类型: Article,,卷期:2011年44-11]
- We report in this article the "arm-first" synthesis of core shell-structured multiarm polyethylene (PE) star polymers having multiple linear-but-branched PE arms joined at a cross-linked polydivinylbenzene (polyDVB) core...
- Well-Defined Amphiphilic Block Copolymers and Nano-objects Formed in Situ via RAFT-Mediated Aqueous Emulsion Polymerization
[作者:Zhang, XW; Boisse, S; Zhang, WJ; Beaunier, P; D'Agosto, F; Rieger, J; Charleux, B,期刊:Macromolecules, 页码:4149-4158 , 文章类型: Article,,卷期:2011年44-11]
- A hydrophilic poly(methacrylic acid-co-poly-(ethylene oxide) methyl ether methacrylate) copolymer with a trithiocarbonate reactive group was used in the free-radical, batch emulsion polymerization of styrene. It allowed ...
- Long-Chain Linear C-19 and C-23 Monomers and Polycondensates from Unsaturated Fatty Acid Esters
[作者:Stempfle, F; Quinzler, D; Heckler, I; Mecking, S,期刊:Macromolecules, 页码:4159-4166 , 文章类型: Article,,卷期:2011年44-11]
- Isomerizing alkoxycarbonylation of methyl oleate and ethyl erucate, respectively, yielded dimethyl 1,19-nonadecanedioate and diethyl 1,23-tricosanedioate in >99% purity. With [kappa(2)-((P) over cap P)Pd(OTf)][OTf] as a ...
- Synthesis and Structure-Property Relationships of Polypropylene-g-poly(ethylene-co-1-butene) Graft Copolymers with Well-Defined Long Chain Branched Molecular Structures
[作者:Wang, L; Wan, D; Zhang, ZJ; Liu, F; Xing, HP; Wang, YH; Tang, T,期刊:Macromolecules, 页码:4167-4179 , 文章类型: Article,,卷期:2011年44-11]
- A series of polypropylene-g-poly(ethylene-co-1-butene) (PP-g-EBR) graft copolymers with well-defined long chain branched (LCB) molecular structures were synthesized via the combination of coordination polymerization and ...
- Retardation in RAFT Polymerization: Does Cross-Termination Occur with Short Radicals Only?
[作者:Ting, SRS; Davis, TP; Zetterlund, PB,期刊:Macromolecules, 页码:4187-4193 , 文章类型: Article,,卷期:2011年44-11]
- The recently proposed model by Perrier and co-workers [J. Polym. Sci., Part A: Polym. Chem. 2009, 47, 3455] to account for retardation effects in dithiobenzoate-mediated reversible addition fragmentation chain transfer (...
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