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  • Novel Amino Acid Based Bifunctional Chiral Phosphines
    [作者:WANG SUXI; HAN XIAOYU; ZHONG FANGRUI; WANG YOUQING; LU YIXIN,期刊:SYNLETT, 页码:2766-2778 , 文章类型: Article,,卷期:2011年-19]
  • As a significant complement to amino catalysts, phosphines are versatile Lewis base catalysts capable of promoting a wide range of diverse organic transformations. In particular, chiral phosphines bearing a Bronsted acid...
  • Radical Addition of Silanes to Alkenes Followed by Oxidation
    [作者:PALFRAMAN MATTHEW J; PARSONS ANDREW F; JOHNSON PAUL,期刊:SYNLETT, 页码:2811-2814 , 文章类型: Article,,卷期:2011年-19]
  • Phenyldimethylsilane and trichlorosilane are shown to undergo efficient radical hydrosilylation reactions, on reaction with various alkenes, using triethylborane as the initiator. Adducts from the trichlorosilane reactio...
  • Phosphomolybdic Acid Catalyzed Synthesis of 1,2,4,5-Tetraoxanes
    [作者:YAN XING; CHEN JINGLEI; ZHU YUNTING; QIAO CHUNHUA,期刊:SYNLETT, 页码:2827-2830 , 文章类型: Article,,卷期:2011年-19]
  • 1,1-Dihydroperoxides were converted into 1,2,4,5-tetraoxanes through condensation with the corresponding ketones in 36-91% yields using phosphomolybdic acid as the catalyst and anhydrous MgSO(4) as the water scavenger.
  • Easy Access to (E)-beta-Ocimene
    [作者:YILDIZHAN SELMA; SCHULZ STEFAN,期刊:SYNLETT, 页码:2831-2833 , 文章类型: Article,,卷期:2011年-19]
  • beta-Ocimene is one of the most common monoterpenes found in Nature, but a simple and reliable synthesis of the pure E-isomer has been missing. Here, we report a simple procedure involving a Grignard coupling as the key ...