- Automated ARGET ATRP Accelerates Catalyst Optimization for the Synthesis of Thiol-Functionalized Polymers
[作者:Siegwart, DJ; Leiendecker, M; Langer, R; Anderson, DG,期刊:Macromolecules, 页码:1254-1261 , 文章类型: Article,,卷期:2012年45-3]
- Conventional synthesis of polymers by ATRP is relatively low throughput, involving iterative optimization of conditions in an inert atmosphere. Automated, high-throughput controlled radical polymerization was developed t...
- Enhancement of Two-Photon Initiating Efficiency of a 4,4 '-Diaminostyryl-2,2 '-bipyridine Derivative Promoted by Complexation with Silver Ions
[作者:Spangenberg, A; Malval, JP; Akdas-Kilig, H; Fillaut, JL; Stehlin, F; Hobeika, N; Morlet-Savary, F; Soppera, O,期刊:Macromolecules, 页码:1262-1269 , 文章类型: Article,,卷期:2012年45-3]
- We report on the two-photon-induced polymerization (TPIP) ability of a new class of free radical two-photon initiator based on a cationic silver(I) complex incorporating 4,4'-diaminostyryl-2,2'-bipyridine (DES) derivativ...
- Rotaxanes from Tetralactams
[作者:Gibson, HW; Wang, H; Niu, ZB; Slebodnick, C; Zhakharov, LN; Rheingold, AL,期刊:Macromolecules, 页码:1270-1280 , 文章类型: Article,,卷期:2012年45-3]
- Attempts to incorporate a tetralactam (3a) into a side-chain polyrotaxane by formation of its complex with p-tritylphenolate and reaction with poly(vinybenzyl chloride) failed, probably due to steric hindrance. However, ...
- Design of Deep Blue Electroluminescent Spiro-Polyfluorenes with High Efficiency by Facilitating the Injection of Charge Carriers through Incorporation of Multiple Charge Transport Moieties
[作者:Huang, CW; Tsai, CL; Liu, CY; Jen, TH; Yang, NJ; Chen, SA,期刊:Macromolecules, 页码:1281-1287 , 文章类型: Article,,卷期:2012年45-3]
- For polymer light-emitting diodes, developing highly efficient, stable, and saturated blue emitting polymer is essential in display and lighting applications and has long been a challenge. Here we report a concept for de...
- Patterning Carbazole-Phenylazomethine Dendrimer Films
[作者:Albrecht, K; Pernites, R; Felipe, MJ; Advincula, RC; Yamamoto, K,期刊:Macromolecules, 页码:1288-1295 , 文章类型: Article,,卷期:2012年45-3]
- The synthesis of double-layer-type dendrimers with carbazole and phenylazomethine as the dendron with a symmetric tetraphenylmethane core is reported. Structural modeling studies showed that the G3 dendrimer has a rigid ...
- Synthesis of a Conjugated Polymer with Broad Absorption and Its Application in High-Performance Phototransistors
[作者:Liu, Y; Wang, HF; Dong, HL; Tan, JH; Hu, WP; Zhan, XW,期刊:Macromolecules, 页码:1296-1302 , 文章类型: Article,,卷期:2012年45-3]
- An amorphous copolymer (PBDT-BBT) of 4,8-bis(2-thienyl)benzo[1,2-b:4,5-b']dithiophene and 5,5'-bibenzo[c][1,2,5]thiadiazole was synthesized by Stile coupling polymerization. PBDT-BBT exhibited good solution processabilit...
- Synthesis and Characterization of New Selenophene-Based Donor-Acceptor Low-Bandgap Polymers for Organic Photovoltaic Cells
[作者:Lee, WH; Son, SK; Kim, K; Lee, SK; Shin, WS; Moon, SJ; Kang, IN,期刊:Macromolecules, 页码:1303-1312 , 文章类型: Article,,卷期:2012年45-3]
- A series of novel thiophene- and selenophene-based low-bandgap polymers were synthesized using a Stile cross-coupling reaction; these polymers contained quinoxaline and diketopyrrolopyrrole as acceptors. Various acceptor...
- Mesogen-Driven Formation of Triblock Copolymer Cylindrical Micelles
[作者:Gao, Y; Li, XY; Hong, LZ; Liu, GJ,期刊:Macromolecules, 页码:1321-1330 , 文章类型: Article,,卷期:2012年45-3]
- Evidences were gathered to support mesogen-driven formation of cylindrical micelles from BCF and ACF triblock copolymers. Here A, B, C, and F denote poly(acrylic acid), poly(tert-butyl acrylate), poly(2-cinnamoyloxylethy...
- Teaching New Tricks to an Old Indicator: pH-Switchable, Photoactive Microporous Polymer Networks from Phenolphthalein with Tunable CO2 Adsorption Power
[作者:Kiskan, B; Antonietti, M; Weber, J,期刊:Macromolecules, 页码:1356-1361 , 文章类型: Article,,卷期:2012年45-3]
- Switchable, organic microporous networks were synthesized by Sonogashira coupling of tetrabromophenolphthalein with 1,4-diethynylenebenzene using optimized reaction conditions. The resulting networks are microporous and ...
- Synthesis and Thermoresponsive Solution Properties of Poly[oligo(ethylene glycol) (meth)acrylamide]s: Biocompatible PEG Analogues
[作者:Chua, GBH; Roth, PJ; Duong, HTT; Davis, TP; Lowe, AB,期刊:Macromolecules, 页码:1362-1374 , 文章类型: Article,,卷期:2012年45-3]
- A library of (meth)acrylamido (co)polymers was prepared by reacting poly(pentafluorophenyl (meth)acrylate) with alpha-amino, omega-methoxy functionalized di(ethylene glycol), tri(ethylene glycol), and poly(ethylene glyco...
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