- Dynamic Ligand Exchange in Reactions of Samarium Diiodide
[作者:SADASIVAM DHANDAPANI V; TEPROVICH JOSEPH A JR; PROCTER DAVID J; FLOWERS ROBERT A,期刊:Organic Letters, 页码:4140-4143 , 文章类型: Article,,卷期:2010年12-18]
- Mechanistic studies show the importance of iodide displacement by additives that accelerate reactions of samarium diiodide. The key feature important for acceleration of reaction rate is the use of proton donors and othe...
- Asymmetric Hydrogenation of Protected Allylic Amines
[作者:STEINHUEBEL DIETRICH P; KRSKA SHANE W; ALORATI ANTHONY; BAXTER JENNY M; BELYK KEVIN; BISHOP BRIAN; PALUCKI MICHAEL; SUN YONGKUI; DAVIES IAN W,期刊:Organic Letters, 页码:4201-4203 , 文章类型: Article,,卷期:2010年12-18]
- A general method for the enantioselective hydrogenation of protected allylic amine derivatives is described. This procedure relies on the generation of a cationic ruthenium complex with the axially chiral ligand (-)-TMBT...
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