The combination of Cu(NO3)(2), potassium hydrogen saccharate (KC6H9O8) and 1,10-phenanthroline (phen) yields a pair of chiral cluster compounds, each with composition Cu-21(C6H5O8)(6)(phen)(12)(NO3)(12)center dot solvate...
Supramolecular strategies, based on hydrogen bonds and ionic interactions, were investigated as tools for the recovery and recycling of homogeneous transition-metal catalysts by using reverse-flow adsorption (RFA) techno...
A series of tris(hydroxymethyl) aminomethane (TRIS)-based linear (bis(TRIS)) and triangular (tris( TRIS)) ligands has been synthesised and were covalently attached to the Wells-Dawson type cluster [P2V3W15O62](9-) to gen...
Lithiated alkoxyallenes, nitriles, and carboxylic acids have been employed as precursors in a three-component reaction leading to highly substituted beta-alkoxy-beta-ketoenamides. Upon treatment with trifluoroacetic acid...
We have investigated the novel single-molecule magnet (NEt4)[Mn-2(5-Brsalen)(2)(MeOH)(2)Cr(CN)(6)] (1; 5-Brsalen= N, N'-ethylenebis(5-bromosalicylidene) iminato anion) using spectroscopic as well as magnetization and sus...
Although many cagelike molecules can create a catalytic environment for promoting chemical reactions, the construction of receptors that can host anionic species and sensitize their reaction is novel. Here we report the ...