- Inhomogeneities and Chain Dynamics in Diene Rubbers Vulcanized with Different Cure Systems
[作者:Valentin, JL; Posadas, P; Fernandez-Torres, A; Malmierca, MA; Gonzalez, L; Chasse, W; Saalwachter, K,期刊:Macromolecules, 页码:4210-4222 , 文章类型: Article,,卷期:2010年43-9]
- In this study, we focus on qualitative differences in the network structure and dynamics of natural as well as poly(butadiene) rubber in dependence of the cure system (sulfur/accelerator or organic peroxide) used in the ...
- PLLA Mesophase and Its Phase Transition Behavior in the PLLA-PEG-PLLA Copolymer As Revealed by Infrared Spectroscopy
[作者:Zhang, JM; Duan, YX; Domb, AJ; Ozaki, Y,期刊:Macromolecules, 页码:4240-4246 , 文章类型: Article,,卷期:2010年43-9]
- A detailed analysis of the IR spectrum of melt-quenched PLLA-PEG-PLLA sample and its change with temperature is presented. It was found that, in the initial state of the melt-quenched PLLA-PEG-PLLA sample, the PLLA const...
- Multi-Length Scale Morphology of Poly(ethylene oxide)-Based Sulfonate Ionomers with Alkali Cations at Room Temperature
[作者:Wang, WQ; Liu, WJ; Tudryn, GJ; Colby, RH; Winey, KI,期刊:Macromolecules, 页码:4223-4229 , 文章类型: Article,,卷期:2010年43-9]
- A series of Li-, Na-, and Cs-neutralized polyester ionomers with well-defined poly(ethylene oxide) (PEO) spacer lengths between sulfonated phthalates have been investigated by X-ray scattering at room temperature. As the...
- Electric Field Induced Gyroid-to-Cylinder Transitions in Concentrated Diblock Copolymer Solutions
[作者:Schmidt, K; Pester, CW; Schoberth, HG; Zettl, H; Schindler, KA; Boker, A,期刊:Macromolecules, 页码:4268-4274 , 文章类型: Article,,卷期:2010年43-9]
- Block copolymers show a variety of microdomain structures due to their ability to phase separate. The bicontinuous gyroid phase and its behavior under the influence of external fields are particularly interesting with re...
- Reversible Morphology Control in Block Copolymer Films via Solvent Vapor Processing: An in Situ GISAXS Study
[作者:Paik, MY; Bosworth, JK; Smilges, DM; Schwartz, EL; Andre, X; Ober, CK,期刊:Macromolecules, 页码:4253-4260 , 文章类型: Article,,卷期:2010年43-9]
- The real time changes occurring within films of cylinder-forming poly(alpha-methylstyrene-block-4-hydroxystyrene) (P alpha MS-b-PHOST) were monitored as they were swollen in tetrahydrofuran (THF) and acetone solvent vapo...
- Characterization of the Photoacid Diffusion Length and Reaction Kinetics in EUV Photoresists with IR Spectroscopy
[作者:Kang, SH; Wu, WL; Choi, KW; De Silva, A; Ober, CK; Prabhu, VM,期刊:Macromolecules, 页码:4275-4286 , 文章类型: Article,,卷期:2010年43-9]
- A soft-contact film transfer method was developed to prepare multilayer photoresist thin films that enable high-resolution spectroscopic and reflectivity measurements for determining the reaction-diffusion kinetic parame...
- Shear Modulus of a Polymer Brush
[作者:Fujii, Y; Yang, ZH; Clough, A; Tsui, OKC,期刊:Macromolecules, 页码:4310-4313 , 文章类型: Article,,卷期:2010年43-9]
- Eighteen years ago. Fredrickson et al, [Macromolecules 1992, 25, 2882-2889] predicted that a molten polymer brush possesses a shear modulus that would cause its surface structure to deviate from a liquid. Their predictio...
- Synthesis and Thermo-/pH- Dual Responsive Properties of Poly(amidoamine) Dendronized Poly(2-hydroxyethyl) Methacrylate
[作者:Gao, M; Jia, XR; Li, Y; Liang, DH; Wei, Y,期刊:Macromolecules, 页码:4314-4323 , 文章类型: Article,,卷期:2010年43-9]
- The first and second generation poly(amidoamine) dendronized poly(2-hydroxylethyl) methacrylate (PGn-macro (n = 1, 2)) were synthesized by the macromonomer approach. The structures and molecular weights of the obtained p...
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