- New Insights into Structure-Property Relationships in Thermosetting Polymers from Studies of Cocured Polycyanurate Networks
[作者:Guenthner, AJ; Lamison, KR; Vij, V; Reams, JT; Yandek, GR; Mabry, JM,期刊:Macromolecules, 页码:211-220 , 文章类型: Article,,卷期:2012年45-1]
- Studies of the physical properties of the cocured networks formed from three similar dicyanate ester monomers revealed a number of unexpected variations from simple linear mixing rules. These variations shed light on imp...
- Preparation of Novel, Nanocomposite Stannoxane-Based Organic-Inorganic Epoxy Polymers containing Ionic bonds
[作者:Strachota, A; Ribot, F; Matejka, L; Whelan, P; Starovoytova, L; Plestil, J; Steinhart, M; Slouf, M; Hromadkova, J; Kovarova, J; Spirkova, M; Strachota, B,期刊:Macromolecules, 页码:221-237 , 文章类型: Article,,卷期:2012年45-1]
- Polymer nanocomposites of epoxies with a novel filler, amino-functional butyltin oxide cage (stannoxane), were prepared and characterized. The nanofiller displays a promising antioxidizing effect, besides mechanical matr...
- Small-Angle X-ray Scattering Study of Charged Triblock Copolymers as a Function of Polymer Concentration, Temperature, and Charge Screening
[作者:Behrens, MA; Kjoniksen, AL; Zhu, KZ; Nystrom, B; Pedersen, JS,期刊:Macromolecules, 页码:246-255 , 文章类型: Article,,卷期:2012年45-1]
- In the current study, the influence of electrostatic interaction on micelle formation has been investigated by characterizing a series of charged thermo-responsive triblock copolymers by densitometry and small-angle X-ra...
- Microphase Separation and Crystallization of All-Conjugated Phenylene-Thiophene Diblock Copolymers
[作者:Yu, XH; Yang, H; Wu, SP; Geng, YH; Han, YC,期刊:Macromolecules, 页码:266-274 , 文章类型: Article,,卷期:2012年45-1]
- Microphase separation and crystallization in thin films of all-conjugated diblock copolymers poly(2,5-dihexyloxy-p-phenylene)-block-(3-hexylthiophene) (PPP-b-P3HT) with various main chain lengths were investigated under ...
- Kinetics and Modeling of Semi-Batch RAFT Copolymerization with Hyperbranching
[作者:Wang, DM; Li, XH; Wang, WJ; Gong, X; Li, BG; Zhu, SP,期刊:Macromolecules, 页码:28-38 , 文章类型: Article,,卷期:2012年45-1]
- This work reports a kinetic model developed to provide insight into branching mechanisms and control of gelation by semibatch controlled radical copolymerization processes. The semibatch RAFT copolymerization of acrylami...
- Directed Self-Assembly of POSS Containing Block Copolymer on Lithographically Defined Chemical Template with Morphology Control by Solvent Vapor
[作者:Tada, Y; Yoshida, H; Ishida, Y; Hirai, T; Bosworth, JK; Dobisz, E; Ruiz, R; Takenaka, M; Hayakawa, T; Hasegawa, H,期刊:Macromolecules, 页码:292-304 , 文章类型: Article,,卷期:2012年45-1]
- Strongly segregating block copolymers (BCPs) are attractive as a means of forming 10 nm scale lithographic features. Here, we report directed self-assembly of polyhedral oligomeric silsesquioxane containing block copolym...
- New Insight to the Mechanism of the Shear-Induced Macroscopic Alignment of Diblock Copolymer Melts by a Unique and Newly Developed Rheo-SAXS Combination
[作者:Meins, T; Hyun, K; Dingenouts, N; Ardakani, MF; Struth, B; Wilhelm, M,期刊:Macromolecules, 页码:455-472 , 文章类型: Article,,卷期:2012年45-1]
- In-situ flow alignment kinetics of a self-assembled lamellar phase polystyrene-block-polyisoprene (PS-b-PI, M(w) = 26 500 g/mol, f(PS) = 51%) diblock copolymer melt has been investigated in detail under mechanical large ...
- A Sugar Decorated Macrornolecular Bottle Brush by Carbohydrate-Initiated Cationic Ring-Opening Polymerization
[作者:Weber, C; Czaplewska, JA; Baumgaertel, A; Altuntas, E; Gottschaldt, M; Hoogenboom, R; Schubert, US,期刊:Macromolecules, 页码:46-55 , 文章类型: Article,,卷期:2012年45-1]
- The capability of a range of protected glucose- (Glc), galactose- (Gal), and fructose- (Fm) based tosylates and triflates to initiate the living cationic ring-opening polymerization of 2-ethy1-2-oxazoline (EtOx) was inve...
- Influence of Metal Ion and Polymer Core on the Melt Rheology of Metallosupramolecular Films
[作者:Kumpfer, JR; Wie, JJ; Swanson, JP; Beyer, FL; Mackay, ME; Rowant, SJ,期刊:Macromolecules, 页码:473-480 , 文章类型: Article,,卷期:2012年45-1]
- Detailed rheological studies of metallosupramolecular polymer films in the melt were performed to elucidate the influence of the metal ion and polymer components on their mechanical and structural properties. 4-Oxy-2,6-b...
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