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  • The synthesis of azadirachtin: a potent insect antifeedant.
    [作者:Ley, Steven V.;Abad-Somovilla, Antonio;Anderson, James C.;Ayats, Carles;Banteli, Rolf;Beckmann, Edith;Boyer, Alistair;Brasca, Maria G.;Brice, Abigail;Broughton, Howard B.;Burke, Brenda J.;Cleator, Ed;Craig, Donald;Denholm, Alastair A.;Denton, Ross M.;Dura,期刊:Chemistry-A European Journal, 页码:10683-10704 , 文章类型: 研究论文,,卷期:2008年14-34]
  • We describe in full the first synthesis of the potent insect antifeedant azadirachtin through a highly convergent approach. An O-alkylation reaction is used to unite decalin ketone and propargylic mesylate fragments, af...
  • Organo group 13 complexes of d-block elements. Part 54.
    [作者:Organometallic chemistry of Ga+: Formation of an Unusual Gallium Dimer in the Coordination Sphere of Ruthenium. Cadenbach, Thomas;Gemel, Christian;Bollermann, Timo;Fernandez, Israel;Frenking, Gernot;Fischer, Roland A.;,期刊:Chemistry-A European Journal, 页码:10789-10796 , 文章类型: 研究论文,,卷期:2008年14-34]
  • New insights into the distinct organometallic chem. of the Ga+ ion are presented. Ga+ reacts as a strong electrophile with the electron rich ligand trismethylene-methane (C(CH2)32-) attached at Ru by insertion into a Ru...
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