- Water-Soluble Iridium(III)-Containing Conjugated Polyelectrolytes with Weakened Energy Transfer Properties for Multicolor Protein Sensing Applications
[作者:Sun, PF; Lu, XM; Fan, QL; Zhang, ZY; Song, WL; Li, B; Huang, L; Peng, JW; Huang, W,期刊:Macromolecules, 页码:8763-8770 , 文章类型: Article,,卷期:2011年44-22]
- Cationic conjugated polyelectrolytes (CPEs) containing an iridium complex ((ppy)(2)Ir(FlPy)) as the energy acceptor were synthesized via Suzuki coupling reaction. The polymer with 12 mol % (ppy)(2)Ir(FlPy) (P4) shows eff...
- 4,4 ',4 ''-Tris(acetoxymethylene)triphenylamine: An Efficient Photoacid Promoted Chemical Cross-Linker for Polyvinylcarbozole and Its Applications for Photolithographic Hole-Transport Materials
[作者:Wang, YX; Leung, MK,期刊:Macromolecules, 页码:8771-8779 , 文章类型: Article,,卷期:2011年44-22]
- A photolithographic hole transport material of 4,4',4 ''-tris(acetoxymethylene)triphenylamine (1), polyvinylcarbazole (PVK), and diphenyliodonium 9,10-dimethoxyanthracene-2-sulfonate (DIAS, a photoacid generator) has bee...
- Reactive Fluorescence Turn-On Probes for Fluoride Ions in Purely Aqueous Media Fabricated from Functionalized Responsive Block Copolymers
[作者:Jiang, YY; Hu, XL; Hu, JM; Liu, H; Zhong, H; Liu, SY,期刊:Macromolecules, 页码:8780-8790 , 文章类型: Article,,卷期:2011年44-22]
- We report on the fabrication of a novel type of responsive double double hydrophilic block copolymer (DHBC)-based highly selective and sensitive fluorescence "turn on" reactive probes for fluoride ions (F(-)) working in ...
- Visible to Near-IR Electrochromism and Photothermal Effect of Poly(3,4-propylenedioxyselenophene)s
[作者:Kim, B; Kim, J; Kim, E,期刊:Macromolecules, 页码:8791-8797 , 文章类型: Article,,卷期:2011年44-22]
- A new selenophene derivative, 3,4-propylenedioxyselenophene (ProDOS), was electropolymerized to a polymeric thin film which demonstrated wide spectral tunability from the visible to near-infrared (NIR) region. The anodic...
- Photovoltaic Performance Improvement of D-A Copolymers Containing Bithiazole Acceptor Unit by Using Bithiophene Bridges
[作者:Zhang, MJ; Guo, X; Li, YF,期刊:Macromolecules, 页码:8798-8804 , 文章类型: Article,,卷期:2011年44-22]
- Two bithiophene-bridged D-A copolymers, PDTSBTBTz and PBDTBTBTz, based on bithiazole acceptor unit and dithienosiole (DTS) or benzodithiophene (BDT) donor unit, were synthesized by the Pd-catalyzed Stille-coupling reacti...
- Dynamic Viscoelasticity of Poly(butyl acrylate) Elastomers Containing Dangling Chains with Controlled Lengths
[作者:Yamazaki, H; Takeda, M; Kohno, Y; Ando, H; Urayama, K; Takigawa, T,期刊:Macromolecules, 页码:8829-8834 , 文章类型: Article,,卷期:2011年44-22]
- We demonstrate that the poly(butyl acrylate) (PBA) elastomers containing considerable amounts of dangling chains with uniform lengths exhibit pronounced viscoelastic relaxation (tan delta > 1) at characteristic frequenci...
- Nanocomposite Materials with Controlled Anisotropic Reinforcement Triggered by Magnetic Self-Assembly
[作者:Robbes, AS; Cousin, F; Meneau, F; Dalmas, F; Boue, F; Jestin, J,期刊:Macromolecules, 页码:8858-8865 , 文章类型: Article,,卷期:2011年44-22]
- Nanocomposite materials filled with nanoparticles currently exhibit two important unsolved experimental challenges: (i) the elaboration of a general strategy allowing to finely tune, for an easy-to-tune range of paramete...
- Counterion Condensation in Nafion
[作者:Beers, KM; Hallinan, DT; Wang, X; Pople, JA; Balsara, NP,期刊:Macromolecules, 页码:8866-8870 , 文章类型: Article,,卷期:2011年44-22]
- Nafion(117) membranes in contact with acidic solutions were characterized by small-angle X-ray scattering and by acid solution uptake measurements. The principle of Donnan equilibrium was used to obtain independent estim...
- Interrupted Helical Structure of Grafted Polypeptides in Brush-Like Macromolecules
[作者:Wang, J; Lu, H; Ren, Y; Zhang, YF; Morton, M; Cheng, JJ; Lin, Y,期刊:Macromolecules, 页码:8699-8708 , 文章类型: Article,,卷期:2011年44-22]
- Brush-like polymers are a type of graft polymers with densely and regularly spaced side chains. Their unique topologies and large sizes afforded a number of potential applications in nanotechnology. Incorporating helical...
- Reversible Complexation Mediated Living Radical Polymerization (RCMP) Using Organic Catalysts
[作者:Gato, A; Suzuki, T; Ohfuji, H; Tanishima, M; Fukuda, T; Tsujii, Y; Kaji, H,期刊:Macromolecules, 页码:8709-8715 , 文章类型: Article,,卷期:2011年44-22]
- A novel class of living radical polymerization using amines as organic catalysts was developed. It is based on a new reversible activation mechanism, reversible complexation (RC). The polymer molecular weight and its dis...
- Kinetic Monte Carlo Modeling of the Sulfinyl Precursor Route for Poly(p-phenylene vinylene) Synthesis
[作者:Van Steenberge, PHM; Vandenbergh, J; D'hooge, DR; Reyniers, MF; Adriaensens, PJ; Lutsen, L; Vanderzande, DJM; Marin, GB,期刊:Macromolecules, 页码:8716-8726 , 文章类型: Article,,卷期:2011年44-22]
- A kinetic Monte Carlo modeling study is presented for precursor polymer formation via the sulfinyl precursor route. The premonomer, 1-(chloromethyl)-4-[(n-octylsulfinyl)methyl]benzene, is subjected to a NatBuO induced 1,...
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