The modular engineering of heterometallic nanoporous metal-organic frameworks (MOFs) based on novel tris-chelate metalloligands, prepared using the functionalised beta-diketone 1,3-bis(4'-cyanophenyl)-1,3-propanedione (H...
This article describes the design, optimisation and development of a continuous flow synthesis of N,N-diethyl-4-(3-fluorophenylpiperidin-4-ylidenemethyl)benzamide, a potent delta-opioid receptor agonist developed by Astr...
Because palladium is widely used in various catalysts and converters, which results in a high level of contamination of water systems and the soil by residual palladium, there is an urgent need for Pd2+-sensitive and -se...
Attractive interactions between a substituted benzene ring and an alpha-substituted acetate group were determined experimentally by using the triptycene model system. The attractive interaction correlates well with the H...
It has previously been shown that recombinant synthesis, under metal-supplemented conditions, of diverse metallothioneins (MTs) results in the recovery of a subpopulation of S2--containing complexes in addition to the S2...
New palladium and platinum metallacycles have been synthesized by reaction between a 2,7-diazapyrenium-based ligand and Pd-II and Pt-II complexes. The inclusion complexes between the metallacycles and polycyclic aromatic...
The development of high-performance molecular electronics and nanotech applications requires deep understanding of atomic level structural, electronic, and magnetic properties of electrode/molecular interfaces. Recent el...
A series of pyridyl guanidinium-carboxylates has been prepared and the dimeric self-assembly of these studied in H2O/DMSO mixtures, principally using dilution isothermal calorimetry. Compounds 5 and 6, incorporating an a...