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  • Stereoselective Olefination Reactions Promoted by Rieke Manganese
    [作者:CONCELLON JOSE M; RODRIGUEZSOLLA HUMBERTO; DEL AMO VICENTE; DIAZ PAMELA,期刊:Synthesis, 页码:2634-2645 , 文章类型: Article,,卷期:2009年-15]
  • A study of the advantages of using manganese, an inexpensive and nontoxic metal, to perform stereoselective beta-elimination reactions and to promote sequential olefination reactions of aldehydes to obtain alpha,beta-uns...
  • Synthesis of Piperidinones through a Radical Cascade
    [作者:GODINEAU EDOUARD; LANDAIS YANNICK,期刊:Synthesis, 页码:2646-2649 , 文章类型: Article,,卷期:2009年-15]
  • Fused piperidinones were assembled from chiral allylsilanes possessing an oxime moiety using a stereocontrolled formal [2+2+2] radical-ionic process. The cascade involves the addition of an alpha-iodo ester to an ene oxi...
  • Facile and Efficient Total Synthesis of Taspine
    [作者:CHENG BIN; ZHANG SANQI; ZHU LIYONG; ZHANG JIE; LI QIANG; SHAN AILIN; HE LANGCHONG,期刊:Synthesis, 页码:2501-2504 , 文章类型: Article,,卷期:2009年-15]
  • The facile and efficient total synthesis of taspine was achieved in 10 steps in high yield (16.5% overall) from commercially available isovanillin. Key steps in the synthesis are preparation of a symmetrical homodimer em...
  • 3-Hydroxy-1H-pyrrole
    [作者:HILL LAWRENCE; IMAM S HAIDER; MCNAB HAMISH; ONEILL WILLIAM J,期刊:Synthesis, 页码:2535-2538 , 文章类型: Article,,卷期:2009年-15]
  • Flash vacuum pyrolysis (FVP) of tert-butyl {[(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ylidene)methyl]amino}acetate at 600 degrees C gives the unstable 3-hydroxy-1H-pyrrole in ca. 55% yield as the only significant product. It...